Modulation of breathing behavior of layered coordination polymers via a solid solution approach: the influence of metal ions on sorption behavior

2014 ◽  
Vol 50 (6) ◽  
pp. 670-672 ◽  
Author(s):  
Gargi Mukherjee ◽  
Kumar Biradha
Keyword(s):  
Solid Solution ◽  
Metal Ions ◽  
Coordination Polymers ◽  
Sorption Behavior ◽  
Solution Approach

scholarly journals A solid solution approach to 2D coordination polymers for CH4/CO2and CH4/C2H6gas separation: equilibrium and kinetic studies

2012 ◽  
Vol 3 (1) ◽  
pp. 116-120 ◽  
Author(s):  
Satoshi Horike ◽  
Yasutaka Inubushi ◽  
Takashi Hori ◽  
Tomohiro Fukushima ◽  
Susumu Kitagawa
Keyword(s):  
Solid Solution ◽  
Coordination Polymers ◽  
Kinetic Studies ◽  
Solution Approach

Control of Emissive Excited States of Silver(I) Halogenido Coordination Polymers by a Solid Solution Approach

2019 ◽  
Vol 58 (13) ◽  
pp. 8419-8431 ◽  
Author(s):  
Masaaki Dosen ◽  
Yoshitaka Kawada ◽  
Seiko Shibata ◽  
Kiyoshi Tsuge ◽  
Yoichi Sasaki ◽  
...  
Keyword(s):  
Solid Solution ◽  
Excited States ◽  
Coordination Polymers ◽  
Solution Approach

Control of Molecular Rotor Rotational Frequencies in Porous Coordination Polymers Using a Solid-Solution Approach

2015 ◽  
Vol 137 (38) ◽  
pp. 12183-12186 ◽  
Author(s):  
Munehiro Inukai ◽  
Tomohiro Fukushima ◽  
Yuh Hijikata ◽  
Naoki Ogiwara ◽  
Satoshi Horike ◽  
...  
Keyword(s):  
Solid Solution ◽  
Coordination Polymers ◽  
Molecular Rotor ◽  
Porous Coordination Polymers ◽  
Solution Approach

Metal-organic Nanopharmaceuticals

2020 ◽  
Vol 8 (3) ◽  
pp. 163-190
Author(s):  
Benjamin Steinborn ◽  
Ulrich Lächelt
Keyword(s):  
Metal Ions ◽  
Coordination Polymers ◽  
Active Agent ◽  
Lewis Base ◽  
High Loading ◽  
Active Components ◽  
Base Functions ◽  
Metal Organic ◽  
Theranostic Applications ◽  
Pharmacologically Active

: Coordinative interactions between multivalent metal ions and drug derivatives with Lewis base functions give rise to nanoscale coordination polymers (NCPs) as delivery systems. As the pharmacologically active agent constitutes a main building block of the nanomaterial, the resulting drug loadings are typically very high. By additionally selecting metal ions with favorable pharmacological or physicochemical properties, the obtained NCPs are predominantly composed of active components which serve individual purposes, such as pharmacotherapy, photosensitization, multimodal imaging, chemodynamic therapy or radiosensitization. By this approach, the assembly of drug molecules into NCPs modulates pharmacokinetics, combines pharmacological drug action with specific characteristics of metal components and provides a strategy to generate tailorable multifunctional nanoparticles. This article reviews different applications and recent examples of such highly functional nanopharmaceuticals with a high ‘material economy’. : Lay Summary: Nanoparticles, that are small enough to circulate in the bloodstream and can carry cargo molecules, such as drugs, imaging or contrast agents, are attractive materials for pharmaceutical applications. A high loading capacity is a generally aspired parameter of nanopharmaceuticals to minimize patient exposure to unnecessary nanomaterial. Pharmaceutical agents containing Lewis base functions in their molecular structure can directly be assembled into metal-organic nanopharmaceuticals by coordinative interaction with metal ions. Such coordination polymers generally feature extraordinarily high loading capacities and the flexibility to encapsulate different agents for a simultaneous delivery in combination therapy or ‘theranostic’ applications.

Hierarchical Hydroxyapatite Microspheres Composed of Nanorods and Their Competitive Sorption Behavior for Heavy Metal Ions

2012 ◽  
Vol 2012 (16) ◽  
pp. 2665-2668 ◽  
Author(s):  
Ronghai Zhu ◽  
Xiaoyong Lai ◽  
Jonathan E. Halpert ◽  
Ranbo Yu ◽  
Dan Wang
Keyword(s):  
Heavy Metal ◽  
Metal Ions ◽  
Heavy Metal Ions ◽  
Sorption Behavior ◽  
Competitive Sorption
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