A tetrastable naphthalenediimide: anion induced charge transfer, single and double electron transfer for combinational logic gates

2013 ◽  
Vol 49 (70) ◽  
pp. 7684 ◽  
Author(s):  
M. R. Ajayakumar ◽  
Geeta Hundal ◽  
Pritam Mukhopadhyay
Keyword(s):  
Electron Transfer ◽  
Charge Transfer ◽  
Logic Gates ◽  
Combinational Logic ◽  
Double Electron ◽  
Induced Charge

A Unimolecular Half-Subtractor Based on Effective Photoinduced Electron Transfer and Intramolecular Charge Transfer Processes of 1,8-Naphthalimide Derivative

2010 ◽  
Vol 63 (2) ◽  
pp. 169 ◽  
Author(s):  
Bing Leng ◽  
He Tian
Keyword(s):  
Electron Transfer ◽  
Charge Transfer ◽  
Photoinduced Electron Transfer ◽  
Fluorescence Spectra ◽  
Intramolecular Charge Transfer ◽  
Logic Gates ◽  
Electron Transfer Process ◽  
Xor Gate ◽  
Fluorescence Characteristics ◽  
Chemical Inputs

We report a unimolecular system as a combinatorial logic half-subtractor based on a naphthalimide derivative. Chemical inputs (OH– and H+) can significantly change the absorption and fluorescence characteristics through modulating intramolecular charge transfer and photoinduced electron transfer process upon protonation or deprotonation of the molecule. An XOR gate is obtained following the absorbance variations at 485 nm, and an INHIBIT gate is induced when the output signal is monitored at 535 nm in the fluorescence spectra. Large differences in output signals allow unequivocal assignment of logic-0 and logic-1 of both logic gates, which may function in parallel to implement the half-subtractor.

Cooperative Absorption-Induced Charge Transfer in a Solid

1990 ◽  
Author(s):  
Isidore Last ◽  
Thomas F. George
Keyword(s):  
Charge Transfer ◽  
Induced Charge

scholarly journals An In-Situ Reaction Route to Molecular Level Dispersed Bisimide and ZnO Nanorod Hybrids with Efficient Photo-Induced Charge Transfer

2021 ◽  
Vol 16 (1) ◽  
Author(s):  
Chunzheng Lv ◽  
Lirong He ◽  
Jiahong Tang ◽  
Feng Yang ◽  
Chuhong Zhang
Keyword(s):  
Charge Transfer ◽  
Electric Field ◽  
Self Assembly ◽  
Molecular Level ◽  
Surface Photovoltage ◽  
Zno Nanorod ◽  
In Situ Reaction ◽  
Perylene Bisimide ◽  
Induced Charge

AbstractAs an important photoconductive hybrid material, perylene/ZnO has attracted tremendous attention for photovoltaic-related applications, but generally faces a great challenge to design molecular level dispersed perylenes/ZnO nanohybrids due to easy phase separation between perylenes and ZnO nanocrystals. In this work, we reported an in-situ reaction method to prepare molecular level dispersed H-aggregates of perylene bisimide/ZnO nanorod hybrids. Surface photovoltage and electric field-induced surface photovoltage spectrum show that the photovoltage intensities of nanorod hybrids increased dramatically for 100 times compared with that of pristine perylene bisimide. The enhancement of photovoltage intensities resulting from two aspects: (1) the photo-generated electrons transfer from perylene bisimide to ZnO nanorod due to the electric field formed on the interface of perylene bisimide/ZnO; (2) the H-aggregates of perylene bisimide in ZnO nanorod composites, which is beneficial for photo-generated charge separation and transportation. The introduction of ordered self-assembly thiol-functionalized perylene-3,4,9,10-tetracarboxylic diimide (T-PTCDI)/ ZnO nanorod composites induces a significant improvement in incident photo-to-electron conversion efficiency. This work provides a novel mentality to boost photo-induced charge transfer efficiency, which brings new inspiration for the preparation of the highly efficient solar cell.

Phosphating-induced charge transfer on CoO/CoP interface for alkaline H2 evolution

2021 ◽  
Author(s):  
Qian Li ◽  
Yuchao Wang ◽  
Jian Zeng ◽  
Qiumei Wu ◽  
Qichen Wang ◽  
...  
Keyword(s):  
Charge Transfer ◽  
H2 Evolution ◽  
Induced Charge
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