Decorating single layer graphene oxide with electron donor and acceptor molecules for the study of photoinduced electron transfer

2013 ◽  
Vol 49 (20) ◽  
pp. 2013 ◽  
Author(s):  
Sushanta K. Das ◽  
Chandra B. KC ◽  
Kei Ohkubo ◽  
Yusuke Yamada ◽  
Shunichi Fukuzumi ◽  
...  
2011 ◽  
Vol 25 (30) ◽  
pp. 4107-4143 ◽  
Author(s):  
C. N. R. RAO ◽  
K. S. SUBRAHMANYAM ◽  
H. S. S. RAMAKRISHNA MATTE ◽  
URMIMALA MAITRA ◽  
KOTA MOSES ◽  
...  

Graphenes with varying number of layers can be synthesized by different strategies. Thus, single-layer graphene is obtained by the reduction of single layer graphene oxide, CVD and other methods besides micromechanical cleavage. Few-layer graphenes are prepared by the conversion of nanodiamond, arcdischarge of graphite and other means. We briefly present the various methods of synthesis and the nature of graphenes obtained. We then discuss the various properties of graphenes. The remarkable property of graphene of quenching fluorescence of aromatic molecules is shown to be associated with photo-induced electron transfer, on the basis of fluorescence decay and time-resolved transient absorption spectroscopic measurements. The interaction of electron donor and acceptor molecules with few-layer graphene samples has been discussed. Decoration of metal nano-particles on graphene sheets and the resulting changes in electronic structure are examined. Few-layer graphenes exhibit ferromagnetic features along with antiferromagnetic properties, independent of the method of preparation. Graphene-like MoS 2 and WS 2 have been prepared by chemical methods, and the materials are characterized by electron microscopy, atomic force microscopy (AFM) and other methods. Boron nitride analogues of graphene have been obtained by a simple chemical procedure starting with boric acid and urea and have been characterized by various techniques.


2019 ◽  
Vol 33 (31) ◽  
pp. 1950384
Author(s):  
Di Lu ◽  
Yu-E Yang ◽  
Weichun Zhang ◽  
Caixia Wang ◽  
Jining Fang ◽  
...  

We have investigated Raman spectra of the G and 2D lines of a single-layer graphene (SLG) with metallic contacts. The shift of the G and 2D lines is correlated to two different factors. Before performing annealing treatment or annealing under low temperature, the electron transfer on graphene surface is dominated by nonuniform strain effect. As the annealing treatment is enhanced, however, a suitable annealing treatment can eliminate the nonuniform strain effect where the relative work function (WF) between graphene and metal becomes a main factor to determine electronic transfer. Moreover, it is confirmed that the optimized annealing treatment can also decrease effectively the structural defect and induced disorder in graphene due to metallic contacts.


CrystEngComm ◽  
2021 ◽  
Author(s):  
Rempei Ando ◽  
Mingoo Jin ◽  
Hajime Ito

Charge-transfer (CT) crystals bearing segregated domains between the electron donor and acceptor molecules are a promising platform for developing new organic functional solid-state materials. However, there is limited diversity in...


2020 ◽  
Vol 180 ◽  
pp. 108449 ◽  
Author(s):  
Dongjun Lv ◽  
Hsiu-Sun Sung ◽  
Xiujing Li ◽  
Xia Zhang ◽  
Zheng Li ◽  
...  

2011 ◽  
Vol 13 (2) ◽  
pp. 674-683 ◽  
Author(s):  
Fernando Blanco ◽  
Ibon Alkorta ◽  
Isabel Rozas ◽  
Mohammad Solimannejad ◽  
José Elguero

2013 ◽  
Vol 29 (7) ◽  
pp. 643-652 ◽  
Author(s):  
Tina Mesarič ◽  
Kristina Sepčič ◽  
Veronica Piazza ◽  
Chiara Gambardella ◽  
Francesca Garaventa ◽  
...  

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