Novel photochemical rearrangement of 2,4,4,6-tetraphenylpyridin-3(4H)-one to an oxazole derivative

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39910001200 ◽

1991 ◽

pp. 1200 ◽

Cited By ~ 2

Author(s):

Yukie Mori ◽

Koko Maeda

Keyword(s):

Photochemical Rearrangement ◽

Oxazole Derivative

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ChemInform Abstract: Novel Photochemical Rearrangement of 2,4,4,6-Tetraphenylpyridin-3(4H)- one to an Oxazole Derivative.

ChemInform ◽

10.1002/chin.199212083 ◽

2010 ◽

Vol 23 (12) ◽

pp. no-no

Author(s):

Y. MORI ◽

K. MAEDA

Keyword(s):

Photochemical Rearrangement ◽

Oxazole Derivative

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ChemInform Abstract: PHOTOCHEMICAL REARRANGEMENT OF PHENYL BENZENESULFONATES

Chemischer Informationsdienst ◽

10.1002/chin.197801119 ◽

1978 ◽

Vol 9 (1) ◽

Author(s):

Y. OGATA ◽

K. TAKAGI ◽

S. YAMADA

Keyword(s):

Photochemical Rearrangement

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Photochemical Rearrangement of Oxaziridines and Nitrones in the Hexahydroindole Series: A Convenient Synthetic Route to 1-Azabicyclo[5.2.0]nonan-2-ones as Novel RGD Mimetics

Organic Letters ◽

10.1021/ol016184j ◽

2001 ◽

Vol 3 (20) ◽

pp. 3067-3070 ◽

Cited By ~ 21

Author(s):

Erika Bourguet ◽

Jean-Louis Baneres ◽

Jean-Pierre Girard ◽

Joseph Parello ◽

Jean-Pierre Vidal ◽

...

Keyword(s):

Synthetic Route ◽

Photochemical Rearrangement

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On the mechanism of the photochemical rearrangement of 3-phenyl substituted cyclopropenes to indenes

Tetrahedron Letters ◽

10.1016/s0040-4039(01)83090-2 ◽

1977 ◽

Vol 18 (33) ◽

pp. 2847-2850 ◽

Cited By ~ 5

Author(s):

Albert Padwa ◽

Roman Loza ◽

Daniel Getman

Keyword(s):

Photochemical Rearrangement

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ChemInform Abstract: BIMANES. 10. PHOTOCHEMICAL REARRANGEMENT OF 1,5-DIAZABICYCLO(3.3.0)OCTA-3,7-DIENE-2,6-DIONES (9,10-DIOXA-ANTI-BIMANES)

Chemischer Informationsdienst ◽

10.1002/chin.198228078 ◽

1982 ◽

Vol 13 (28) ◽

Author(s):

H. KANETY ◽

H. DODIUK ◽

E. M. KOSOWER

Keyword(s):

Photochemical Rearrangement

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PHOTOCHEMICAL REARRANGEMENT OF 3-PHENYLATED 2(3H)-OXEPINONES IN ACIDIC MEDIA. FORMATION OF 5-STYRYL-2(5H)-FURANONES

Chemistry Letters ◽

10.1246/cl.1979.1291 ◽

1979 ◽

Vol 8 (10) ◽

pp. 1291-1294 ◽

Cited By ~ 3

Author(s):

Nobuto Hoshi ◽

Hisahiro Hagiwara ◽

Hisashi Uda

Keyword(s):

Acidic Media ◽

Photochemical Rearrangement

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Photochemical Rearrangement ofN-Chlorolactams: A Route toN-Heterocycles through Concerted Ring Contraction

The Journal of Organic Chemistry ◽

10.1021/jo100181h ◽

2010 ◽

Vol 75 (8) ◽

pp. 2610-2618 ◽

Cited By ~ 26

Author(s):

Dana K. Winter ◽

Alexandre Drouin ◽

Jean Lessard ◽

Claude Spino

Keyword(s):

Ring Contraction ◽

Photochemical Rearrangement

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An unusual abnormal Wolff rearrangement

Canadian Journal of Chemistry ◽

10.1139/v03-039 ◽

2003 ◽

Vol 81 (6) ◽

pp. 517-524 ◽

Cited By ~ 4

Author(s):

Howard E Zimmerman ◽

Pengfei Wang

Keyword(s):

Reaction Mechanism ◽

Ab Initio ◽

Transition Structure ◽

Wolff Rearrangement ◽

Photochemical Rearrangement ◽

Bicyclic Structure

An unusual example of the abnormal Wolff rearrangement was studied. The bicyclic structure of the reactant and intermediates precluded some mechanistic possibilities of this unusual Abnormal Wolff Rearrangement. The study involved the photochemical rearrangement of diazodehydronorbornone bearing phenyl and 2-pyridyl groups at C-7. A number of examples of interesting stereoselectivity were encountered. The mechanism was investigated by use of ab initio QST type computations which located a unique transition structure species accounting for the reaction mechanism.Key words: abnormal-Wolff, carbene, rearrangement, QM computations, reaction mechanism.

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