Catalytic properties of lanthanide metals introduced into Y-zeolites

Insight into tri-coordinated aluminum dependent catalytic properties of dealuminated Y zeolites in oxidative desulfurization

Applied Catalysis B Environmental ◽

10.1016/j.apcatb.2021.120022 ◽

2021 ◽

Vol 288 ◽

pp. 120022

Author(s):

Zhiguo Zhu ◽

Haikuo Ma ◽

Weiping Liao ◽

Pengpeng Tang ◽

Kaixuan Yang ◽

...

Keyword(s):

Catalytic Properties ◽

Oxidative Desulfurization ◽

Y Zeolites ◽

Insight Into

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Structural and Catalytic Properties of the Alkali Metal Ion-Exchanged Y-Zeolites by 29Si and 27Al Solid-State NMR and FT-IR Spectroscopy

Key Engineering Materials ◽

10.4028/www.scientific.net/kem.277-279.708 ◽

2005 ◽

Vol 277-279 ◽

pp. 708-719

Author(s):

Chang Seop Lee ◽

Hee Jung Lee ◽

Sung Woo Choi ◽

Jahun Kwak ◽

Charles H.F. Peden

Keyword(s):

Solid State ◽

Alkali Metal ◽

Photoelectron Spectroscopy ◽

Metal Ion ◽

Nmr Spectra ◽

Catalytic Properties ◽

Nox Reduction ◽

29Si Nmr ◽

Y Zeolites ◽

X Ray

A series of cation exchanged Y-zeolites were prepared by exchanging cations with various alkali (M+, M= Li, Na, K, Cs) metals. The structural and catalytic properties of the alkali metal exchanged Y-zeolites have been investigated by a number of analytical techniques. Comparative elemental analyses were determined by an Energy Dispersive Spectroscopy X-ray (EDS), X-ray Photoelectron Spectroscopy (XPS), Inductively Coupled Plasma-Atomic Emission Spectroscopy (ICP-AES) and X-ray Fluorescence (XRF) before and after cation substitution. The framework and non-framework Al coordination and the Si/Al ratios of the Y-zeolites were investigated by MAS Solid-State Nuclear Magnetic Resonance (NMR) spectroscopy. The Al NMR spectra were characterized by two 27Al resonance signals at 12 and 59 ppm, indicating the presence of the non-framework and framework Al respectively. The intensities of these resonances were used to monitor the amount of the framework and non-framework Al species in the series of exchanged zeolites. The 29Si NMR spectra were characterized by four resonance signals at -79, -84, -90, and -95 ppm. Changing the alkali metal cations in the exchanged Y-zeolites significantly altered the extent of the octahedral/tetrahedral coordination and the Si/Al ratio. The Fourier Transform Infrared spectra of the CO2 adsorbed on to the exchanged Y-zeolites showed a low frequency shift, as the atomic number of the exchanged alkali metal increased. In addition, the catalytic activity of these samples for NOx reduction were tested in combination with a non-thermal plasma technique and interpreted based on the above structural and spectroscopic information.

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Catalytic properties of calcium-neodymium type Y zeolites in toluene disproportionation reaction

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science ◽

10.1007/bf00926300 ◽

1975 ◽

Vol 24 (1) ◽

pp. 98-103

Author(s):

Ya. I. Isakov ◽

Kh. M. Minachev ◽

N. Ya. Usachev

Keyword(s):

Catalytic Properties ◽

Disproportionation Reaction ◽

Y Zeolites ◽

Toluene Disproportionation

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Catalytic properties of X and Y zeolites in condensation of butyraldehyde

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science ◽

10.1007/bf00953914 ◽

1985 ◽

Vol 34 (9) ◽

pp. 1812-1817 ◽

Cited By ~ 1

Author(s):

Ya. I. Isakov ◽

N. Ya. Usachev ◽

T. A. Isakova ◽

Kh. M. Minachev

Keyword(s):

Catalytic Properties ◽

Y Zeolites

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Influence of CO2 on the catalytic properties of types X and Y zeolites

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science ◽

10.1007/bf00923492 ◽

1974 ◽

Vol 23 (4) ◽

pp. 736-746

Author(s):

Kh. M. Minachev ◽

Ya. I. Isakov

Keyword(s):

Catalytic Properties ◽

Y Zeolites

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Catalytic Properties of Fluorine Modified SmNa-Y Zeolites

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19920781 ◽

1992 ◽

Vol 57 (4) ◽

pp. 781-787 ◽

Cited By ~ 3

Author(s):

Stanisłav Kowalak ◽

Maria Pawłowska ◽

Kenneth J. Balkus

Keyword(s):

Catalytic Properties ◽

Acid Sites ◽

Y Zeolites ◽

Cumene Cracking ◽

Toluene Disproportionation ◽

Zeolite Nay ◽

Polyvalent Cations ◽

Protonic Acid ◽

Acid Catalyzed ◽

Catalyzed Reactions

It is known that mild fluorination of zeolites, including those modified with polyvalent cations, increases their activity for acid catalyzed reactions. In this study we report the reactivity of fluorine modified Sm(III) exchanged zeolite NaY. Mild fluorination of SmNaY reduces the activity of strong protonic acid sites and increases the contribution of weak aprotic acid centres. Results for cumene cracking and toluene disproportionation as well as for 1-hexene isomerization are reported.

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