Reactions of organometallic complexes included in cyclodextrins: reactivity of alkyldicarbonyl(η5-cyclopentadienyl)iron complexes towards carbon monoxide and sulphur dioxide in the solid state

1991 ◽  
pp. 263-264 ◽  
Author(s):  
Masayuki Shimada ◽  
Akira Harada ◽  
Shigetoshi Takahashi
Keyword(s):  
Carbon Monoxide ◽  
Solid State ◽  
Sulphur Dioxide ◽  
Iron Complexes ◽  
Organometallic Complexes

Über die Koordination von Kohlenmonoxid an Bis(dithiolato)-Eisen-Komplexen [1] / On the Coordination of Carbon Monoxide on Bis(dithiolato)-Iron Complexes [1]

1978 ◽  
Vol 33 (2) ◽  
pp. 190-196 ◽  
Author(s):  
D. Sellmann ◽  
P. Kreutzer ◽  
E. Unger
Keyword(s):  
Carbon Monoxide ◽  
Solid State ◽  
Oxidation State ◽  
Alkaline Medium ◽  
Mass Spectra ◽  
Iron Complexes ◽  
Solution Temperature ◽  
H Nmr ◽  
Iron Salts ◽  
Elemental Analyses

The reaction of CO with iron salts in the presence of benzene-dithiol depends on the oxidation state of iron, pH of the solution, temperature and CO pressure. In alkaline EtOH one obtains labile cis-[Fe(CO)2(C6H4S2)2]2- complexes, which cannot be isolated in the solid state. On acidifying, oxidizing with O2 or heating the solution, the CO ligands are split off; after reduction with NaBH4, CO can be co-ordinated again at pH > 7 under normal conditions. Reacting benzene-1-thiomethyl-2-thiol in alkaline medium with Fe2+ and CO yields the isolable [cis-Fe(CO)2(CH3S-C6H4-S)2], which is characterized by elemental analyses, IR, 1H NMR and mass spectra. It is a labile complex coordinating CO reversibly

scholarly journals Selective reduction and homologation of carbon monoxide by organometallic iron complexes

2018 ◽  
Vol 9 (1) ◽  
Author(s):  
Helen R. Sharpe ◽  
Ana M. Geer ◽  
Laurence J. Taylor ◽  
Benjamin M. Gridley ◽  
Toby J. Blundell ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Selective Reduction ◽  
Iron Complexes

Bis(1-phenyl-1-propyne) complexes of tungsten(II): crystal structures of [WI2(CO)(NCR)(η2-MeC2Ph)2] (R = Me, Et, or Ph)

2001 ◽  
Vol 79 (3) ◽  
pp. 263-271
Author(s):  
Paul K Baker ◽  
Michael GB Drew ◽  
Deborah S Evans
Keyword(s):  
Carbon Monoxide ◽  
Solid State ◽  
Crystal Structures ◽  
Octahedral Geometry ◽  
X Ray ◽  
X Ray Crystallography ◽  
Alkyne Complexes ◽  
First Time

Reaction of [WI2(CO)3(NCMe)2] with two equivalents of 1-phenyl-1-propyne (MeC2Ph) in CH2Cl2, and in the absence of light, gave the bis(1-phenyl-1-propyne) complex [WI2(CO)(NCMe)(η2-MeC2Ph)2] (1) in 77% yield. Treatment of equimolar quantities of 1 and NCR (R = Et, i-Pr, t-Bu, Ph) in CH2Cl2 afforded the nitrile-exchanged products, [WI2(CO)(NCR)(η2-MeC2Ph)2] (2-5) (R = Et (2), i-Pr (3), t-Bu (4), Ph (5)). Complexes 1, 2, and 5 were structurally characterized by X-ray crystallography. All three structures have the same pseudo-octahedral geometry, with the equatorial sites being occupied by cis and parallel alkyne groups, which are trans to the cis-iodo groups. The trans carbon monoxide and acetonitrile ligands occupy the axial sites. In structures 1 and 2, the methyl and phenyl substituents of the 1-phenyl-1-propyne ligands are cis to each other, whereas for the bulkier NCPh complex (5), the methyl and phenyl groups are trans to one another. This is the first time that this arrangement has been observed in the solid state in bis(alkyne) complexes of this type.Key words: bis(1-phenyl-1-propyne), carbonyl, nitrile, diiodo, tungsten(II), crystal structures.

Reduction of sulphur dioxide using carbon monoxide over gold supported catalysts

Gold Bulletin ◽  
2018 ◽  
Vol 51 (4) ◽  
pp. 153-162 ◽  
Author(s):  
Thelma Ngwenya ◽  
Isaac Nongwe ◽  
Linda L. Jewell
Keyword(s):  
Carbon Monoxide ◽  
Sulphur Dioxide ◽  
Supported Catalysts

An electrical solid-state sulphur dioxide vapour sensor based on a polyvinyl alcohol formaldehyde composite

2017 ◽  
Vol 5 (11) ◽  
pp. 2871-2882 ◽  
Author(s):  
Sudesna Chakravarty ◽  
Arpan Datta ◽  
Neelotpal Sen Sarma
Keyword(s):  
Solid State ◽  
Polyvinyl Alcohol ◽  
Polymer Composite ◽  
Sulphur Dioxide ◽  
Gas Sensing ◽  
Sensor Material ◽  
Solid State Sensor ◽  
Coumarin 6

Polyvinyl alcohol-formaldehyde–coumarin 6 (PVFCOU) polymer composite as a novel solid-state sensor material for SO2 gas sensing.

Photoluminescence of platinum(II) diethynylphenanthroline organometallic complexes with bis-arylethynyl derivatives in solution and solid state

2019 ◽  
Vol 880 ◽  
pp. 116-123 ◽  
Author(s):  
Michito Shiotsuka ◽  
Rikuo Ono ◽  
Yoshihiro Kurono ◽  
Taiki Asano ◽  
Yusuke Sakae
Keyword(s):  
Solid State ◽  
Organometallic Complexes

scholarly journals IoT Based Underground Drainage Monitoring System

2020 ◽  
Vol 9 (3) ◽  
pp. 247-249
Keyword(s):  
Carbon Monoxide ◽  
Nitrogen Oxide ◽  
Monitoring System ◽  
Hydrogen Sulphide ◽  
Sulphur Dioxide ◽  
Smart Phone ◽  
Threshold Value ◽  
Ammonia Nitrogen ◽  
Network System

Underground drainage monitoring system plays an important role in keeping the cities clean and healthy. Compared to other countries, India consists of highest number of sewage workers. Exposure of sewage workers to poisonous gases like hydrogen sulphide, sulphur dioxide, carbon monoxide, methane, ammonia, nitrogen oxide increases the death of the sewage workers. The main aim of this project is to design a network system which helps in monitoring poisonous gases present in sewage. Whenever the gas level crosses the threshold value, the information with different gas ppm values is displayed in the smart phone through the app. It also indicates whether it is safe for the manual scavengers to work in the environment or not.

A post-synthetic approach triggers selective and reversible sulphur dioxide adsorption on a metal–organic framework

2018 ◽  
Vol 54 (65) ◽  
pp. 9063-9066 ◽  
Author(s):  
Marta Mon ◽  
Estefanía Tiburcio ◽  
Jesús Ferrando-Soria ◽  
Rodrigo Gil San Millán ◽  
Jorge A. R. Navarro ◽  
...  
Keyword(s):  
Solid State ◽  
Cation Exchange ◽  
Sulphur Dioxide ◽  
Metal Organic Framework ◽  
Exchange Process ◽  
Synthetic Approach ◽  
Metal Organic ◽  
Organic Framework

We report the application of a post-synthetic solid-state cation-exchange process to afford a novel 3D MOF with hydrated barium cations hosted at pores able to trigger selective and reversible SO2adsorption.

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