Synthesis and crystal structure of [Ru3Pt(µ-PPh2)(µ4-η2-CCBut)(CO)7(dppe)](dppe = Ph2PCH2CH2PPh2), a butterfly cluster containing an unusually bonded alkynyl ligand: a model for an intermediate molecular geometry in a cluster-ligand rearrangement

1991 ◽  
pp. 163-165 ◽  
Author(s):  
Louis J. Farrugia ◽  
Neil MacDonald ◽  
Robert D. Peacock
Keyword(s):  
Crystal Structure ◽  
Molecular Geometry ◽  
Synthesis And Crystal Structure ◽  
Butterfly Cluster

scholarly journals Synthesis and Crystal Structure of 6-Bromo-2-(furan-2-yl)-3-(prop-2-ynyl)-3H-imidazo[4,5-b]pyridine

2013 ◽  
Vol 2013 ◽  
pp. 1-5 ◽  
Author(s):  
Youssef Kandri Rodi ◽  
Santiago V. Luis ◽  
Inés Martí ◽  
Vicente Martí-Centelles ◽  
Younès Ouzidan
Keyword(s):  
Crystal Structure ◽  
Crystal And Molecular Structure ◽  
Crystal Packing ◽  
Molecular Geometry ◽  
Monoclinic Space Group ◽  
X Ray Diffraction ◽  
Synthesis And Crystal Structure ◽  
X Ray ◽  
Cell Parameters ◽  
Primary Focus

The crystal and molecular structure of 6-bromo-2-(furan-2-yl)-3-(prop-2-ynyl)-3H-imidazo[4,5-b]pyridine (C13H8BrN3O) has been investigated from single crystal X-ray diffraction data. The primary focus is to investigate the molecular geometry of this compound in the solid state along with the associated intermolecular hydrogen bonding and relatedπ-πinteractions present in the crystal packing. This compound crystallizes in the monoclinic space groupP21/nwith cell parameters:a= 4.39655(19) Å,b= 13.5720(5) Å,c= 20.0471(5) Å,β= 94.753(3),V= 1192.10(7) Å3,D= 1.683 g·cm−3, andZ= 4. The crystal structure is stabilized byπ-πinteractions and intermolecular C–H⋯N and C–H⋯O interactions.

Synthesis and Crystal Structure of a New Butterfly Cluster [Rh2Co2 (CO)6(μ-CO)4(μ4,η2-HC≡CFeCp2)]

2002 ◽  
Vol 2002 (7) ◽  
pp. 328-329
Author(s):  
Bao-Hua Zhu ◽  
Bin Hu ◽  
Wei-Qiang Zhang ◽  
Yuan-Qi Yin ◽  
Jie Sun
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
X Ray Diffraction ◽  
Synthesis And Crystal Structure ◽  
X Ray ◽  
Butterfly Cluster

The new butterfly cluster [Rh2Co2(CO)6(μ-CO)4(μ4, η2-HC≡CFeCp2)] 3 was obtained by the reaction of [Rh2Co2(CO)12] 1 with the 1-alkyne ligand HC≡CFeCp2 2, and the structure of cluster 3 has been established by single-crystal X-ray diffraction methods.

Synthesis and crystal structure of [MnL(μ-Cl)MnCl3]·H2O L=N, N'-bis(2'-pyridine)methyl-1,10-phenanthroline-2,9-dimethanamine

2002 ◽  
Vol 2002 (3) ◽  
pp. 120-121
Author(s):  
Tian Fu Liu ◽  
Hua Kuan Lin ◽  
Shou Rong Zhu ◽  
Zhong Ming Wang ◽  
Hong Gen Wang ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Synthesis And Crystal Structure

Synthesis and crystal structure of an 18-Mo girdle-like polyoxomolybdate

2002 ◽  
Vol 2002 (3) ◽  
pp. 107-109 ◽  
Author(s):  
Guang Liu ◽  
Jian Liu ◽  
Shi-Wei Zhang
Keyword(s):  
Crystal Structure ◽  
Synthesis And Crystal Structure

The Synthesis and Crystal Structure of Aluminum Selenite Trihydrate, Al2(seO3)3.32O

1992 ◽  
Author(s):  
W. T. Harrison ◽  
G. D. Stucky ◽  
R. E. Morris ◽  
A. K. Cheetham
Keyword(s):  
Crystal Structure ◽  
Synthesis And Crystal Structure

scholarly journals High-pressure synthesis and crystal structure of the mixed-cation borate Ga4In4B15O33(OH)3

2019 ◽  
Vol 74 (4) ◽  
pp. 357-363
Author(s):  
Daniela Vitzthum ◽  
Hubert Huppertz
Keyword(s):  
Crystal Structure ◽  
High Pressure ◽  
High Temperature ◽  
Diffraction Data ◽  
X Ray Diffraction ◽  
Synthesis And Crystal Structure ◽  
X Ray ◽  
Mixed Cation ◽  
High Pressure High Temperature ◽  
Pressure Synthesis

AbstractThe mixed cation triel borate Ga4In4B15O33(OH)3 was synthesized in a Walker-type multianvil apparatus at high-pressure/high-temperature conditions of 12.5 GPa and 1300°C. Although the product could not be reproduced in further experiments, its crystal structure could be reliably determined via single-crystal X-ray diffraction data. Ga4In4B15O33(OH)3 crystallizes in the tetragonal space group I41/a (origin choice 2) with the lattice parameters a = 11.382(2), c = 15.244(2) Å, and V = 1974.9(4) Å3. The structure of the quaternary triel borate consists of a complex network of BO4 tetrahedra, edge-sharing InO6 octahedra in dinuclear units, and very dense edge-sharing GaO6 octahedra in tetranuclear units.

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