The synthesis and structure of the alkaline earth metal organic compounds [M(OAr)2(thf)n][M = Ca, n= 3 (1) or 0; M = Ba, n= 4] and [{Ca(NR2)(µNR2)(thf)}2], and the X-ray structure of (1)(Ar = C6H2But2-2,6-Me-4; R = SiMe3; thf - OC4H8)

1990 ◽  
pp. 1141-1142 ◽  
Author(s):  
Peter B. Hitchcock ◽  
Michael F. Lappert ◽  
Gerard A. Lawless ◽  
Beatriz Royo
Keyword(s):  
Organic Compounds ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
X Ray ◽  
Metal Organic

Alkaline earth metal-based metal–organic framework: hydrothermal synthesis, X-ray structure and heterogeneously catalyzed Claisen–Schmidt reaction

2014 ◽  
Vol 43 (34) ◽  
pp. 13006-13017 ◽  
Author(s):  
Debraj Saha ◽  
Tanmoy Maity ◽  
Subratanath Koner
Keyword(s):  
Hydrothermal Synthesis ◽  
Alkaline Earth ◽  
Metal Organic Framework ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Schmidt Reaction ◽  
X Ray ◽  
Chelidamic Acid ◽  
Metal Organic ◽  
Organic Framework

Two alkaline earth metal based carboxylate framework systems, [Mg(HL)(H2O)2]n (1) and [Ca(H2L)2]n (2) (H3L = chelidamic acid) have been hydrothermally synthesized and characterized. Both compound 1 and its dehydrated species heterogeneously catalyze Claisen–Schmidt reaction.

Two new alkaline earth metal organic frameworks with the diamino derivative of biphenyl-4,4′-dicarboxylate as bridging ligand: Structures, fluorescence and quenching by gas phase aldehydes

Polyhedron ◽  
2018 ◽  
Vol 153 ◽  
pp. 173-180 ◽  
Author(s):  
Stavros A. Diamantis ◽  
Anastasia D. Pournara ◽  
Antonios G. Hatzidimitriou ◽  
Manolis J. Manos ◽  
Giannis S. Papaefstathiou ◽  
...  
Keyword(s):  
Gas Phase ◽  
Alkaline Earth ◽  
Metal Organic Frameworks ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Bridging Ligand ◽  
Metal Organic

Über Erdalkalimetalloxogallate, VI Zum Problem der Mischkristallbildung zwischen CaGa2O4 und CaAl2O4 / On Alkaline Earth Metal Oxogallates, VI About Mixed Crystal Formation of CaGa2O4-CaAl2O4

1976 ◽  
Vol 31 (12) ◽  
pp. 1604-1606 ◽  
Author(s):  
Hk. Müller-Buschbaum ◽  
W. Schmachtel
Keyword(s):  
Single Crystal ◽  
Alkaline Earth ◽  
Mixed Crystal ◽  
Earth Metal ◽  
Mixed Crystals ◽  
Alkaline Earth Metal ◽  
Crystal Formation ◽  
X Ray ◽  
Mixed Crystal Formation

Mixed crystals of the formulae CaGaAlO4 (1) and CaGa0.5Al1.5O4 (2) were investigated by X-ray single crystal work. 1 shows a tetrahedral orientation like that of CaGa2O4 (monokl.), 2 another one of CaAl2O4. A discussion of the different polyhedral arrangement of the stuffed tridymite structures is given.

Synthesis, crystal structure, and fluorescence property of two alkaline-earth metal organic complexes

2017 ◽  
Vol 47 (10) ◽  
pp. 1392-1397 ◽  
Author(s):  
Xue-Min Jing ◽  
Guo-Ping Yang ◽  
Qiu-Xiang Zhou ◽  
Fu-Cai Dai ◽  
Li-Lei Ren
Keyword(s):  
Crystal Structure ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Fluorescence Property ◽  
Alkaline Earth Metal ◽  
Organic Complexes ◽  
Metal Organic
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