First structural characterisation of a transition metal complex containing a bridging PCR(CO) ligand (R = But). Synthesis, crystal, and molecular structure of [Fe2(CO)5(µ-dppm){µ-η2-PCBut(CO)}](dppm = Ph2PCH2PPh2)

1989 ◽  
pp. 1660-1661 ◽  
Author(s):  
Peter B. Hitchcock ◽  
Timothy J. Madden ◽  
John F. Nixon
Keyword(s):  
Molecular Structure ◽  
Transition Metal ◽  
Metal Complex ◽  
Transition Metal Complex ◽  
Crystal And Molecular Structure ◽  
Structural Characterisation

scholarly journals Crystal and molecular structure of the binuclear Rh(I) complex (μ-Cl)(μ-pz) [Rh(CO)2]2 (pz = pyrazolyl, N2C3H3). An example of molecular stacking via weak intermolecular interactions

1985 ◽  
Vol 63 (3) ◽  
pp. 688-691 ◽  
Author(s):  
Brenda M. Louie ◽  
Steven J. Rettig ◽  
Alan Storr ◽  
James Trotter
Keyword(s):  
Molecular Structure ◽  
Transition Metal ◽  
Metal Complex ◽  
Physical Properties ◽  
Transition Metal Complex ◽  
Crystal And Molecular Structure ◽  
Heavy Atom ◽  
Full Matrix ◽  
Weak Intermolecular Interactions ◽  
Molecular Stacking

Details of the synthesis and physical properties of (μ-Cl)(μ-pz)[Rh(CO)2]2 are given. Crystals of (μ-chloro) (μ-pyrazolyl)-bis(dicarbonylrhodiumd(I)) are monoclinic, a = 7.0970(8), b = 20.5184(10), c = 15.808(2) Å, β = 94.695(6)°, Z = 8, space group P21/c. The structure was solved by conventional heavy-atom methods and was refined by full-matrix least-squares procedures to R = 0.035 and Rw = 0.038 for 2949 reflections with I ≥ 3σ(I). The complex provides a rare example of molecular stacking in a binuclear transition metal complex with [Formula: see text] distances of 3.5107(8) and 3.6201(8) Å.

[4-tBu-2,6-{P(O)(OiPr)2}2C6H2Sn(PPh3)Cr(CO)5]ClO4 – a salt containing a cationic triphenylphosphane-stabilized organostannylene transition metal complex

2015 ◽  
Vol 38 (5-6) ◽  
Author(s):  
Michael Wagner ◽  
Thomas Zöller ◽  
Christina Dietz ◽  
Klaus Jurkschat
Keyword(s):  
Molecular Structure ◽  
Transition Metal ◽  
Metal Complex ◽  
Transition Metal Complex

AbstractThe isolation and molecular structure of bis(di-

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