The unusual course of the reactions of phosphorus pentachloride with 1-phosphorylated alcohols and acetals

1989 ◽  
pp. 1549 ◽  
Author(s):  
Mukattis B. Gazizov ◽  
Rafail A. Khairullin
Keyword(s):  
Phosphorus Pentachloride

ChemInform Abstract: REACTION OF PHOSPHORUS PENTACHLORIDE WITH DIVINYL SULFIDE

1982 ◽  
Vol 13 (42) ◽  
Author(s):  
S. V. FRIDLAND ◽  
I. A. SHKURAI ◽  
L. I. LAPTEVA
Keyword(s):  
Phosphorus Pentachloride ◽  
Divinyl Sulfide

ChemInform Abstract: REACTION OF PHOSPHORUS PENTACHLORIDE WITH KETENE AND ALKOXYACETYLENES

1978 ◽  
Vol 9 (22) ◽  
Author(s):  
M. A. KAZANKOVA ◽  
T. YA. SATINA ◽  
V. D. LUN'KOV ◽  
I. F. LUTSENKO
Keyword(s):  
Phosphorus Pentachloride

Phosphorus pentachloride-induced substitution and fragmentation of a γ-pyrone

1975 ◽  
Vol 12 (1) ◽  
pp. 219-220 ◽  
Author(s):  
Gerald A. Poulton ◽  
Mary E. Williams
Keyword(s):  
Phosphorus Pentachloride

Phosphorus Pentachloride Initiated Functionalization of Silicon Nanocrystals

Langmuir ◽  
2017 ◽  
Vol 33 (35) ◽  
pp. 8766-8773 ◽  
Author(s):  
Muhammad Amirul Islam ◽  
Md Hosnay Mobarok ◽  
Regina Sinelnikov ◽  
Tapas K. Purkait ◽  
Jonathan G. C. Veinot
Keyword(s):  
Silicon Nanocrystals ◽  
Phosphorus Pentachloride

ChemInform Abstract: REACTIONS OF ALKENES WITH PHOSPHORUS PENTACHLORIDE AND TRICHLOROSILANE

1976 ◽  
Vol 7 (21) ◽  
pp. no-no
Author(s):  
A. F. KOLOMIETS ◽  
A. V. FOKIN ◽  
A. A. KROLEVETS ◽  
O. V. BRONNYI
Keyword(s):  
Phosphorus Pentachloride

ChemInform Abstract: REACTION OF PHOSPHORUS PENTACHLORIDE WITH ALKENES

1978 ◽  
Vol 9 (51) ◽  
Author(s):  
A. V. FOKIN ◽  
A. F. KOLOMIETS ◽  
A. A. KROLEVETS
Keyword(s):  
Phosphorus Pentachloride

Reactions of Phosphorus Pentachloride with Ethyl-, Vinyl-, and Ethynyl(trichloromethyl)carbinol and with 1,1,1-Trichloro-3-nonyn-2-ol

1973 ◽  
Vol 51 (12) ◽  
pp. 2017-2023 ◽  
Author(s):  
E. Wilkins Reeve ◽  
Thomas F. Steckel
Keyword(s):  
Vapor Phase ◽  
Acid Chloride ◽  
Phosphorus Pentachloride ◽  
Hydroxyl Group ◽  
Phosphate Ester ◽  
Allylic Rearrangement ◽  
Ethyl Vinyl ◽  
Normal Product

Reactions of phosphorus pentachloride with ethyl(trichloromethyl)carbinol (2), (trichloromethyl)-vinylcarbinol (7), ethynyl(trichloromethyl)carbinol (11a), and 1,1,1-trichloro-3-nonyn-2-ol (11b) have been studied. Whereas the reaction of phenyl(trichloromethyl)carbinol with phosphorus pentachloride leads to a nearly quantitative replacement of the hydroxyl group by chlorine, the reactions of the aliphatic (trichloromethyl)carbinols are more complicated. Thus the reaction of 2 with phosphorus pentachloride gave 18% of the normal product, 1,1,1,2-tetrachlorobutane (3), 13% of 1,1,2-trichloro-1-butene (4) from a dehydrohalogenation, and a higher boiling phosphate ester – acid chloride mixture. The alkynylcarbinols (11) gave tetrachlorobutynes (12) as well as tetrachloroallenes (13) by allylic rearrangement. A crystalline phosphate ester of 11a was also isolated. Several examples are given of catalytic rearrangements in the vapor phase of 1,1,1-trichloro-2-alkenes to 1,1,3-trichloro-1-alkenes.

Sign in / Sign up

Export Citation Format

Share Document