Two monomeric, octahedral complexes of alkaline earth metal salts: syntheses, physical characteristics, and crystal structures of Srl2·4HMPA and Sr(NCS)2·4HMPA [HMPA = O : P(NMe2)3]

Author(s):  
Donald Barr ◽  
Alan T. Brooker ◽  
Michael J. Doyle ◽  
Simon R. Drake ◽  
Paul R. Raithby ◽  
...  
CrystEngComm ◽  
2017 ◽  
Vol 19 (45) ◽  
pp. 6787-6796 ◽  
Author(s):  
Éric Quarez ◽  
Élise Deunf ◽  
Vincent Cadiou ◽  
Thibaut Gutel ◽  
Florent Boucher ◽  
...  

Li, Na and Mg salts of 2,5-(dianilino)terephthalate exhibit systematically an original double layered structure composed of polar and non-polar slabs.


2016 ◽  
Vol 128 (11) ◽  
pp. 1765-1774 ◽  
Author(s):  
BIKSHANDARKOIL R SRINIVASAN ◽  
KIRAN T DHAVSKAR ◽  
CHRISTIAN NÄTHER

2013 ◽  
Vol 30 ◽  
pp. 1-4 ◽  
Author(s):  
Elliot Combs ◽  
Basak Cinlar ◽  
Yomaira Pagan-Torres ◽  
James A. Dumesic ◽  
Brent H. Shanks

1989 ◽  
Vol 44 (5) ◽  
pp. 519-525 ◽  
Author(s):  
Hans-Jürgen Meyer ◽  
Joachim Pickardt

By reaction of methanolic solutions of hexamethylenetetramine with aqueous solutions of hexacyanoferrates(III) of strontium and barium resp., crystals of the compounds were obtained. Sr3[Fe(CN)6]2 · 3 C6H12N4 · 18 H2O, tetragonal, space group P42/nmc, Z = 4, a = 1931.8(4), c = 1579.9(4) pm, 1358 reflections. R = 0.066. Ba3[Fe(CN)6]2 · 2 C6H12N4 · 11 Η2Ο. monoclinic. space group P21/n, Ζ = 2, a = 1148.0(4), b = 1369.7(4), c = 1584.5(4) pm, γ = 95.79(3)°, 2583 reflections, R = 0.057. The crystal structures of these adducts are compared with those of other hexamethylenetetramine adducts of alkaline and alkaline earth metal hexacyanoferrates of the general formula M,[Fe(CN)6]y · zC6H12N4 · vH2O recently investigated by us. A structural model for the adducts is presented.


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