Spectroscopic properties and redox chemistry of the phosphorescent excited state of [Au2(dppm)2]2+[dppm = bis(diphenylphosphino)methane]

1989 ◽  
pp. 885 ◽  
Author(s):  
Chi-Ming Che ◽  
Hoi-Lun Kwong ◽  
Vivian Wing-Wah Yam ◽  
Kar-Cheong Cho
Keyword(s):  
Excited State ◽  
Redox Chemistry ◽  
Spectroscopic Properties

Synthesis and properties of diads based on tetra-aryl porphyrins and ruthenium bis-terpyridine-type complexes

2001 ◽  
Vol 05 (07) ◽  
pp. 600-607 ◽  
Author(s):  
ISABELLE M. DIXON ◽  
JEAN-PAUL COLLIN
Keyword(s):  
Energy Transfer ◽  
Excited State ◽  
Fluorescence Quenching ◽  
Emission Spectra ◽  
Spectroscopic Properties ◽  
Free Base ◽  
Strong Electron ◽  
Transfer Processes ◽  
C Complex

Four diads consisting of a free-base or zinc aryl-porphyrin associated with two ruthenium(II) bis(terdentate) complexes (non-cyclometallated Ru ( N 6) or cylometallated Ru ( N 5 C )) have been synthesized. The strong electron-withdrawing properties of the Ru ( N 6) as compared to the Ru ( N 5 C ) complex have been illustrated by their electrochemical and spectroscopic properties. Emission spectra of the diads and the reference compounds have shown that very efficient fluorescence quenching occurs, probably by energy transfer processes from the porphyrin to the 3MLCT excited state of the ruthenium unit.

scholarly journals 2-(benzimidazol-2-yl)-3-hydroxychromone derivatives: spectroscopic properties and a possibile alternative intramolecular proton phototransfer

2008 ◽  
Vol 6 (3) ◽  
pp. 443-449 ◽  
Author(s):  
D. Svechkarev ◽  
G. Karpushina ◽  
L. Lukatskaya ◽  
A. Doroshenko
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Experimental Evidence ◽  
Spectroscopic Properties ◽  
Intramolecular Proton Transfer ◽  
Fluorescent Properties ◽  
Theoretical Possibility ◽  
Proton Phototransfer

AbstractThree 2-(benzimidazol-2-yl)-3-hydroxychromone derivatives were synthesized. Their spectroscopic and fluorescent properties, due to excited state intramolecular proton transfer (ESIPT) from OH to carbonyl, were studied. Theoretical possibility of an alternative intramolecular H-bonding and experimental evidence for such behavior are discussed.

scholarly journals Chromophore-labelled, luminescent platinum complexes: syntheses, structures, and spectroscopic properties

2016 ◽  
Vol 45 (25) ◽  
pp. 10297-10307 ◽  
Author(s):  
Oliver J. Stacey ◽  
Benjamin D. Ward ◽  
Simon J. Coles ◽  
Peter N. Horton ◽  
Simon J. A. Pope
Keyword(s):  
Excited State ◽  
Platinum Complexes ◽  
Spectroscopic Properties ◽  
Emission Lifetime ◽  
P Ligands

Ligands based upon 4-carboxamide-2-phenylquinoline have been functionalised with naphthyl, anthracenyl and pyrenyl chromophores. The pyrene appended Pt(ii) complex shows excited state equilibration and a long emission lifetime.

Synthesis and Spectroscopic Properties of Some Compounds Related to Benzenamine-4-(9-anthryl)-N,N-dimethyl [ADMA]

1987 ◽  
Vol 42 (4) ◽  
pp. 395-405 ◽  
Author(s):  
N. Detzer ◽  
W. Baumann ◽  
B. Schwager ◽  
J.-C. Fröhling ◽  
C. Brittinger
Keyword(s):  
Dipole Moment ◽  
Excited State ◽  
Electric Field ◽  
Ir Spectra ◽  
Spectroscopic Properties ◽  
State Model ◽  
Polar State ◽  
Two State Model ◽  
Excited State Dipole Moment ◽  
Good Agreement

The synthesis of several compounds related to ADMA are described in detail. These compounds are characterized by their mass, NMR, and IR-spectra. In addition, the solvent dependent shift of the fluorescence as well as the effect of an electric field on the fluorescence have been measured. The results are in agreement with a two-state model assuming the simultaneous fluorescence from a weakly polar and a highly polar state with dipole moment μ. μ2/a3 (a is Onsager’s radius) has been determined from both effects. The results are in good agreement with an excited state dipole moment of about 60 • 10-30Cm, in the polar state.

Synthesis and spectroscopic properties of benzo- and naphthofuryl-3-hydroxychromones

2001 ◽  
Vol 79 (4) ◽  
pp. 358-363 ◽  
Author(s):  
Andrey S Klymchenko ◽  
Turan Ozturk ◽  
Vasyl G Pivovarenko ◽  
Alexander P Demchenko
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Spectroscopic Properties ◽  
Molecular Probe ◽  
Absorption Bands ◽  
Methyl Group ◽  
Long Wavelength ◽  
Excited State Proton Transfer ◽  
Wavelength Absorption ◽  
Long Wavelength Absorption Band

With the focus of designing new fluorescent probes, four new 3-hydroxy-chromone derivatives bearing benzofuran and naphthofuran groups were synthesized. They show bathochromic absorption shifts relative to 3-hydroxyflavone with the ability of retention to display the excited-state proton transfer. Disruption of the planarity by the methyl group in the furan ring leads to a decrease of both the extinction coefficient and the contribution of long wavelength absorption band, while molecules without a methyl group showed two distinct absorption bands. Shifts to longer wavelengths are also observed in fluorescent spectra, and the absence of the methyl group results in a dramatic increase of fluorescence quantum yield and lifetime. Of the extended 3-hydroxychromone derivatives, 3-hydroxy-2-naphtho[2,1-b]furan-2-yl-chromone has shown comparable, and in some cases better, absorption and fluorescence properties than the 3-hydroxychromones synthesized so far, which make it a highly promising candidate as molecular probe for analytical chemistry, biophysics, and cellular biology.Key words: benzo- and naphthofuryl-3-hydroxyflavone, synthesis, electronic spectra, fluorescence, excited state proton transfer.

scholarly journals Micro-Solvated DMABN: Excited State Quantum Dynamics and Dual Fluorescence Spectra

Molecules ◽  
2021 ◽  
Vol 26 (23) ◽  
pp. 7247
Author(s):  
Sandra Gómez ◽  
Esra N. Soysal ◽  
Graham A. Worth
Keyword(s):  
Electronic Structure ◽  
Excited State ◽  
Quantum Dynamics ◽  
Computational Study ◽  
Water Solution ◽  
Fluorescence Emission ◽  
Spectroscopic Properties ◽  
Complete Analysis ◽  
Solvent Molecules ◽  
Dynamics Simulations

In this work, we report a complete analysis by theoretical and spectroscopic methods of the short-time behaviour of 4-(dimethylamino)benzonitrile (DMABN) in the gas phase as well as in cyclohexane, tetrahydrofuran, acetonitrile, and water solution, after excitation to the La state. The spectroscopic properties of DMABN were investigated experimentally using UV absorption and fluorescence emission spectroscopy. The computational study was developed at different electronic structure levels and using the Polarisable Continuum Model (PCM) and explicit solvent molecules to reproduce the solvent environment. Additionally, excited state quantum dynamics simulations in the diabatic picture using the direct dynamics variational multiconfigurational Gaussian (DD-vMCG) method were performed, the largest quantum dynamics “on-the-fly” simulations performed with this method until now. The comparison with fully converged multilayer multiconfigurational time-dependent Hartree (ML-MCTDH) dynamics on parametrised linear vibronic coupling (LVC) potentials show very similar population decays and evolution of the nuclear wavepacket. The ring C=C stretching and three methyl tilting modes are identified as the responsible motions for the internal conversion from the La to the Lb states. No major differences are observed in the ultrafast initial decay in different solvents, but we show that this effect depends strongly on the level of electronic structure used.

scholarly journals Calculating Franck Condon Factor and Potential Curves for X2Σ+-A2Π System of BeBr Molecule

2015 ◽  
Vol 52 ◽  
pp. 5-10
Author(s):  
Adil Nameh Ayaash
Keyword(s):  
Excited State ◽  
Potential Function ◽  
Dissociation Energy ◽  
Ground State ◽  
Spectroscopic Properties ◽  
Spectroscopic Constants ◽  
Condon Factor ◽  
Condon Factors ◽  
Franck Condon ◽  
Potential Curves

The present work concerns by study of spectroscopic properties for Beryllium monobromide BeBr. Franck Condon Factor of BeBr molecule had been calculated theoretically for ground state X2Σ+ and excited state A2Π by special integrals by depending on spectroscopic constants for this molecule. The Dissociation energy and potential curves of this molecule is studied in this work by using Hua potential function, the results of potential curves and Franck Condon Factors converge with other researchers results.

Sign in / Sign up

Export Citation Format

Share Document