Existence of 2-carboxyphenyldiphenylarsine oxide as a novel resonance hybrid structure with strong intermolecular hydrogen bonding dissociating to the first example of a monocyclic acyloxyhydroxyarsorane in chloroform

1987 ◽  
pp. 685
Author(s):  
Harinder K. Bathla ◽  
Swarn S. Parmar ◽  
Harveen K. Saluja ◽  
Alexandra M. Z. Slawin ◽  
David J. Williams
Keyword(s):  
Hydrogen Bonding ◽  
Hybrid Structure ◽  
Intermolecular Hydrogen Bonding ◽  
Resonance Hybrid

scholarly journals Exploring the Structural Chemistry of Pyrophosphoramides: N,N′,N″,N‴-Tetraisopropylpyrophosphoramide

Chemistry ◽  
2021 ◽  
Vol 3 (1) ◽  
pp. 149-163
Author(s):  
Duncan Micallef ◽  
Liana Vella-Zarb ◽  
Ulrich Baisch
Keyword(s):  
Crystal Structure ◽  
Mass Spectrometry ◽  
Nuclear Magnetic Resonance ◽  
Hydrogen Bonding ◽  
Nmr Spectroscopy ◽  
Ir Spectroscopy ◽  
Room Temperature ◽  
Intermolecular Hydrogen Bonding ◽  
X Ray Diffraction ◽  
X Ray

N,N′,N″,N‴-Tetraisopropylpyrophosphoramide 1 is a pyrophosphoramide with documented butyrylcholinesterase inhibition, a property shared with the more widely studied octamethylphosphoramide (Schradan). Unlike Schradan, 1 is a solid at room temperature making it one of a few known pyrophosphoramide solids. The crystal structure of 1 was determined by single-crystal X-ray diffraction and compared with that of other previously described solid pyrophosphoramides. The pyrophosphoramide discussed in this study was synthesised by reacting iso-propyl amine with pyrophosphoryl tetrachloride under anhydrous conditions. A unique supramolecular motif was observed when compared with previously published pyrophosphoramide structures having two different intermolecular hydrogen bonding synthons. Furthermore, the potential of a wider variety of supramolecular structures in which similar pyrophosphoramides can crystallise was recognised. Proton (1H) and Phosphorus 31 (31P) Nuclear Magnetic Resonance (NMR) spectroscopy, infrared (IR) spectroscopy, mass spectrometry (MS) were carried out to complete the analysis of the compound.

Intra- and Intermolecular Hydrogen Bonding in 2-Phosphinylphenol:  A Quantum Chemical Study

1998 ◽  
Vol 102 (1) ◽  
pp. 274-279 ◽  
Author(s):  
Jack B. Levy ◽  
Ned H. Martin ◽  
István Hargittai ◽  
Magdolna Hargittai
Keyword(s):  
Hydrogen Bonding ◽  
Quantum Chemical ◽  
Quantum Chemical Study ◽  
Chemical Study ◽  
Intermolecular Hydrogen Bonding
Sign in / Sign up

Export Citation Format

Share Document