The monocation and monoanion of Re2(µ-Cl)2(µ-dppm)2Cl4(dppm = Ph2PCH2PPh2). An unusual pair of complexes possessing metal–metal bond orders of 1.5 that differ in electronic configuration

1985 ◽  
Vol 0 (3) ◽  
pp. 114-116 ◽  
Author(s):  
Kim R. Dunbar ◽  
Douglas Powell ◽  
Richard A. Walton
Keyword(s):  
Electronic Configuration ◽  
Bond Orders ◽  
Metal Bond ◽  
Metal Metal

Metal–metal bond distances and bond orders in dimanganese complexes with bidentate ligands: scope for some very short Mn–Mn bonds

2020 ◽  
Vol 44 (30) ◽  
pp. 12993-13006 ◽  
Author(s):  
Fitzerald Hujon ◽  
R. H. Duncan Lyngdoh ◽  
R. Bruce King
Keyword(s):  
Bond Orders ◽  
Bidentate Ligands ◽  
Bond Lengths ◽  
Metal Bond ◽  
Metal Metal

“Super-short” Mn–Mn bonds are reported here, the shortest Mn–Mn bond lengths reported so far in any study.

scholarly journals Stabilizing Three-Center Single-Electron Metal-Metal Bond in a Fullerene Cage

2021 ◽  
Author(s):  
Shangfeng Yang ◽  
Fei Jin ◽  
Jinpeng Xin ◽  
Runnan Guan ◽  
Xiao-Ming Xie ◽  
...  
Keyword(s):  
Rare Earth ◽  
Electronic Configuration ◽  
Single Electron ◽  
Fullerene Cage ◽  
Endohedral Fullerenes ◽  
Metal Bond ◽  
Metal Metal

Trimetallic carbide clusterfullerenes (TCCFs) encapsulating a quinary M3C2 cluster represent a special family of endohedral fullerenes with open-shelled electronic configuration. Herein, a novel TCCF based on a medium-sized rare earth...

Binuclear Cobalt Paddlewheel-Type Complexes: Relating Metal–Metal Bond Lengths to Formal Bond Orders

2020 ◽  
Author(s):  
Fitzerald Hujon ◽  
R. H. Duncan Lyngdoh ◽  
Henry F. Schaefer ◽  
R. Bruce King
Keyword(s):  
Bond Orders ◽  
Bond Lengths ◽  
Metal Bond ◽  
Metal Metal

Raman intensities and metal-metal bond orders

1970 ◽  
Vol 9 (5) ◽  
pp. 1045-1049 ◽  
Author(s):  
Carl O. Quicksall ◽  
Thomas G. Spiro
Keyword(s):  
Bond Orders ◽  
Metal Bond ◽  
Metal Metal ◽  
Raman Intensities
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