Cluster chemistry. Synthesis and X-ray crystal structure of [Fe3(CO)9(µ3-η2-CNBut)], a trinuclear cluster complex containing an isocyanide ligand acting as a six-electron donor

Author(s):  
Michael I. Bruce ◽  
Trevor W. Hambley ◽  
Brian K. Nicholson
Polyhedron ◽  
1984 ◽  
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Anthony D. Miles ◽  
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Brian W Skelton ◽  
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1986 ◽  
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MI Bruce ◽  
MR Snow ◽  
ERT Tiekink

The crystal structure of OsPt2(μ-CO)3(CO)2(PPh3)3 has been determined by single-crystal X-ray diffraction techniques. Crystals are triclinic, space group Pī with unit cell dimensions a 13.593(4), b 15.839(4), c 12.633(8) Ǻ, α 102.97(3), β 108.18(2), γ 84.86(3)° with Z2. The structure was refined by a full-matrix least-squares procedure on 5896 reflections [I ≥ 2.5σ(I)] to final R 0.028 and Rw 0.034. A triphenylphosphine ligand binds each of the metal atoms disposed at the corners of a triangle. Each metal-metal bond is spanned by a bridging carbonyl group. The coordination about the osmium atom is completed by two terminal carbonyl groups.


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