Dimerisation of a diplatinum to a tetraplatinum complex during catalysis of the water gas shift reaction: the X-ray crystal structure of [Pt4(µ2-CO)2(µ2-Ph2PCH2PPh2)3{Ph2PCH2P(:O)Ph2}]

1982 ◽  
pp. 198-200 ◽  
Author(s):  
Aileen A. Frew ◽  
Ross H. Hill ◽  
Ljubica Manojlović-Muir ◽  
Kenneth W. Muir ◽  
Richard J. Puddephatt
Keyword(s):  
Crystal Structure ◽  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
X Ray ◽  
Shift Reaction ◽  
Water Gas

In situ time-resolved X-ray diffraction studies of Fe[sub 2]O[sub 3] and Cu, Cr-Fe[sub 2]O[sub 3] catalysts for the water-gas shift reaction

2009 ◽  
Author(s):  
Daniela Zanchet ◽  
Cristiane B. Rodella ◽  
Laura J. S. Lopes ◽  
Marco A. Logli ◽  
Valéria P. Vicentini ◽  
...  
Keyword(s):  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
X Ray Diffraction ◽  
Time Resolved ◽  
X Ray ◽  
Shift Reaction ◽  
Water Gas

Importance of the Metal-Oxide Interface in Catalysis: In Situ Studies of the Water-Gas Shift Reaction by Ambient-Pressure X-ray Photoelectron Spectroscopy

2013 ◽  
Vol 125 (19) ◽  
pp. 5205-5209 ◽  
Author(s):  
Kumudu Mudiyanselage ◽  
Sanjaya D. Senanayake ◽  
Leticia Feria ◽  
Shankhamala Kundu ◽  
Ashleigh E. Baber ◽  
...  
Keyword(s):  
Metal Oxide ◽  
Photoelectron Spectroscopy ◽  
Ambient Pressure ◽  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
Oxide Interface ◽  
X Ray ◽  
Shift Reaction ◽  
Water Gas

H2 production through the water-gas shift reaction: An in situ time-resolved X-ray diffraction investigation of manganese OMS-2 catalyst

2010 ◽  
Vol 156 (1-2) ◽  
pp. 2-7 ◽  
Author(s):  
Shanthakumar Sithambaram ◽  
Wen Wen ◽  
Eric Njagi ◽  
Xiong-Fei Shen ◽  
Jonathan C. Hanson ◽  
...  
Keyword(s):  
H2 Production ◽  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
X Ray Diffraction ◽  
Time Resolved ◽  
X Ray ◽  
Shift Reaction ◽  
Water Gas

Importance of the Metal-Oxide Interface in Catalysis: In Situ Studies of the Water-Gas Shift Reaction by Ambient-Pressure X-ray Photoelectron Spectroscopy

2013 ◽  
Vol 52 (19) ◽  
pp. 5101-5105 ◽  
Author(s):  
Kumudu Mudiyanselage ◽  
Sanjaya D. Senanayake ◽  
Leticia Feria ◽  
Shankhamala Kundu ◽  
Ashleigh E. Baber ◽  
...  
Keyword(s):  
Metal Oxide ◽  
Photoelectron Spectroscopy ◽  
Ambient Pressure ◽  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
Oxide Interface ◽  
X Ray ◽  
Shift Reaction ◽  
Water Gas

scholarly journals Hydrogen Production from the Water-Gas Shift Reaction on Iron Oxide Catalysts

2014 ◽  
Vol 2014 ◽  
pp. 1-6 ◽  
Author(s):  
R. Bouarab ◽  
S. Bennici ◽  
C. Mirodatos ◽  
A. Auroux
Keyword(s):  
Iron Oxide ◽  
Diffuse Reflectance ◽  
Water Gas Shift ◽  
Water Gas Shift Reaction ◽  
X Ray Diffraction ◽  
Acid Base ◽  
X Ray ◽  
Diffuse Reflectance Infrared ◽  
Shift Reaction ◽  
Water Gas

Unsupported and supported iron oxide catalysts were prepared by incipient wetness impregnation method and studied in the water-gas shift reaction (WGSR) in the temperature range 350–450°C. The techniques of characterization employed were BET, X-ray diffraction, acid-base measurements by microcalorimetry and in situ diffuse reflectance infrared Fourier transform spectroscopy. MgO, TiO2, or SiO2 was added in order to (i) obtain a catalyst exempt of chromium oxide and (ii) study the effect of their acid-base properties on catalytic activity of Fe2O3. X-ray diffraction studies, and calorimetric and diffuse reflectance infrared Fourier transform measurements reveal a complete change in the physicochemical properties of the iron oxide catalyst after MgO addition due to the formation of the spinel oxide phase. These results could indicate that the MgFe2O4 phase stabilizes the reduced iron phase, preventing its sintering under realistic WGSR conditions (high H2O partial pressures).

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