Asymmetric reduction of αβ-unsaturated ketones with lithium aluminium hydride partially decomposed by (–)-N-methylephedrine and N-ethylaniline

1980 ◽  
Vol 0 (21) ◽  
pp. 1026-1027 ◽  
Author(s):  
Shiro Terashima ◽  
Norihiko Tanno ◽  
Kenji Koga
Keyword(s):  
Asymmetric Reduction ◽  
Lithium Aluminium Hydride ◽  
Unsaturated Ketones ◽  
Lithium Aluminium

ASYMMETRIC REDUCTION OF ACETOPHENONE WITH CHIRAL HYDRIDE REAGENT PREPARED FROM LITHIUM ALUMINIUM HYDRIDE AND (S)-2-(ANILINOMETHYL)PYRROLIDINE

1977 ◽  
Vol 6 (7) ◽  
pp. 783-786 ◽  
Author(s):  
Teruaki Mukaiyama ◽  
Masatoshi Asami ◽  
Jun-ichi Hanna ◽  
Susumu Kobayashi
Keyword(s):  
Asymmetric Reduction ◽  
Lithium Aluminium Hydride ◽  
Lithium Aluminium

Asymmetric reduction of p-alkylacetophenones

1986 ◽  
Vol 51 (3) ◽  
pp. 684-686 ◽  
Author(s):  
Otakar Červinka ◽  
Anna Fábryová ◽  
Ivana Brožová ◽  
Miroslav Holík
Keyword(s):  
Asymmetric Reduction ◽  
Optically Active ◽  
Lithium Aluminium Hydride ◽  
Lithium Aluminium

Asymmetric reduction of p-alkylacetophenones Ia-VIIa with lithium aluminium hydride in the presence of (-)-quinine affords optically active alcohols Ib-VIIb of the (R)-(+) configuration in optical yields of about 50%.

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