‘Organic metals’: alkylthio substitution effects in tetrathiafulvalene–tetracyanoquinodimethane charge-transfer complexes

1978 ◽  
pp. 18-19 ◽  
Author(s):  
Masao Mizuno ◽  
Anthony F. Garito ◽  
Michael P. Cava
Keyword(s):  
Charge Transfer ◽  
Substitution Effects ◽  
Charge Transfer Complexes ◽  
Organic Metals

Organic Metals: N,N'-Dicyano-1,4-benzoquinonediimines as Acceptors in Charge-Transfer Complexes

1985 ◽  
Vol 120 (1) ◽  
pp. 309-314 ◽  
Author(s):  
Giovanni D. Andreetti ◽  
Silvia Bradamante ◽  
Paolo Costa Bizzarri ◽  
Giorgio A. Pagani
Keyword(s):  
Charge Transfer ◽  
Charge Transfer Complexes ◽  
Organic Metals

Mixed valency in organic charge transfer complexes

2007 ◽  
Vol 366 (1862) ◽  
pp. 139-150 ◽  
Author(s):  
Gunzi Saito ◽  
Tsuyoshi Murata
Keyword(s):  
Charge Transfer ◽  
Mixed Valence ◽  
Charge Transfer Complexes ◽  
Partial Charge ◽  
Key Factors ◽  
Partial Charge Transfer ◽  
Mixed Valency ◽  
Ionic System ◽  
Organic Metals ◽  
Transfer State

Mixed-valence (partial charge transfer state) and segregated stacking are the key factors for constructing organic metals. Here, we discuss the ionicity phase diagrams for a variety of charge transfer systems to provide a strategy for the development of functional organic materials (Mott insulator, semiconductor, superconductor, metal, complex isomer, neutral–ionic system, etc.).

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