Synthesis of a branched pentasaccharide: one of the core oligosaccharides of human blood-group substances

Author(s):  
Claudine Augé ◽  
Serge David ◽  
Alain Veyrières
1982 ◽  
Vol 60 (1) ◽  
pp. 68-75 ◽  
Author(s):  
R. U. Lemieux ◽  
S. Z. Abbas ◽  
B. Y. Chung

Trisaccharides related to the core chain of human blood group determinants were synthesized by way of the phthalimido-chloride method; namely, β-D-Galp-(1 → 3)-β-D-GlcNAcp-(1 → 6)-D-Galp (3), β-D-Galp-(1 → 3)-β-D-GlcNAcp-(1 → 3)-D-Galp (5), β-D-Galp-(1 → 4)-β-D-GlcNAcp-(1 → 6)-D-Galp (4), and β-D-Galp-(1 → 4)-β-D-GlcNAcp-(1 → 3)-D-Galp (6). The syntheses of the 8-methoxy-carbonyloctyl β-glycosides of these trisaccharides are also reported.


Nature ◽  
1948 ◽  
Vol 162 (4119) ◽  
pp. 579-580 ◽  
Author(s):  
D. AMINOFF ◽  
W. T. J. MORGAN

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