One-electron reduction of cobalt(III) hexa-ammine ion by hydroxymethyl radicals in aqueous solution

1974 ◽  
pp. 938 ◽  
Author(s):  
Kent R. Olson ◽  
Morton Z. Hoffman
Keyword(s):  
Aqueous Solution ◽  
Hydroxymethyl Radicals ◽  
Electron Reduction

ChemInform Abstract: ONE-ELECTRON REDUCTION OF PENTACYANONITROSYLFERRATE(II) ION IN AQUEOUS SOLUTION

1977 ◽  
Vol 8 (49) ◽  
Author(s):  
R. P. CHENEY ◽  
M. G. SIMIC ◽  
M. Z. HOFFMAN ◽  
I. A. TAUB ◽  
K.-D. ASMUS
Keyword(s):  
Aqueous Solution ◽  
Electron Reduction

One-electron reduction of tris(2,2'-bipyrimidine)ruthenium(2+) ion in aqueous solution: a photochemical, radiation chemical, and electrochemical study

1989 ◽  
Vol 93 (16) ◽  
pp. 6080-6088 ◽  
Author(s):  
Gilda Neshvad ◽  
Morton Z. Hoffman ◽  
Quinto G. Mulazzani ◽  
Margherita Venturi ◽  
Mauro Ciano ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Electrochemical Study ◽  
Radiation Chemical ◽  
Electron Reduction

ChemInform Abstract: ONE-ELECTRON REDUCTION OF AROMATIC NITROGEN HETEROCYCLES IN AQUEOUS SOLUTION. 2,2′-BIPYRIDINE AND 1,10-PHENANTHROLINE

1979 ◽  
Vol 10 (39) ◽  
Author(s):  
Q. G. MULAZZANI ◽  
S. EMMI ◽  
P. G. FUOCHI ◽  
M. VENTURI ◽  
M. Z. HOFFMAN ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Nitrogen Heterocycles ◽  
Electron Reduction

Generation of rhodium(II) and rhodium(I) from the one-electron reduction of tris(2,2'-bipyridine)rhodium(III) ion in aqueous solution

1981 ◽  
Vol 103 (12) ◽  
pp. 3362-3370 ◽  
Author(s):  
Quinto G. Mulazzani ◽  
Silvano Emmi ◽  
Morton Z. Hoffman ◽  
Margherita Venturi
Keyword(s):  
Aqueous Solution ◽  
Electron Reduction ◽  
The One

The kinetics of the electrodeposition of cadmium telluride

1984 ◽  
Vol 37 (4) ◽  
pp. 689 ◽  
Author(s):  
WJ Danaher ◽  
LE Lyons
Keyword(s):  
Aqueous Solution ◽  
Cadmium Telluride ◽  
Second Step ◽  
Disc Electrode ◽  
Electron Reduction ◽  
Kinetics Of ◽  
Rotating Ring Disc Electrode

The kinetics of the electrodeposition of CdTe from an aqueous solution containing CdSO4, TeO2 and H2SO4 were investigated by using a rotating ring-disc electrode. The results for tellurium deposition alone indicated that the reaction occurs through a six-electron reduction of HTeO2+ to H2Te, followed by a reaction between H,2Te and HTeO2+ yielding tellurium. At HTeO2+ concentrations greater than 10-3 M, the second step of this process is very fast and the overall reaction behaves as a four-electron reduction of HTeO2+ to Te: only at lower HTeO2+ concentrations was evidence observed for the six-electron reduction. The electrodeposition of CdTe occurs through two possible pathways: Cd2+ ions can react with H2Te produced during the reduction of HTeO2+ and thus yield CdTe, or tellurium deposited on the electrode can react with Cd2+ to yield CdTe. The two reactions compete with the deposition of pure tellurium. Conditions to deposit stoichiometric CdTe are suggested.

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