Photoelectron spectroscopic evidence concerning ground-state through-σ-bond interaction in the 1,3-diaza-adamantan-6-one system

1974 ◽  
Vol 0 (18) ◽  
pp. 725-726 ◽  
Author(s):  
Tadashi Sasaki ◽  
Shoji Eguchi ◽  
Tsutomo Kiriyama ◽  
Yoji Sakito ◽  
Hiroshi Kato
Keyword(s):  
Ground State ◽  
Spectroscopic Evidence ◽  
Bond Interaction

Spectroscopic Evidence for a Triplet Ground State in the Naphthyl Cation

2011 ◽  
Vol 123 (31) ◽  
pp. 7142-7145 ◽  
Author(s):  
Héctor Alvaro Galué ◽  
Jos Oomens
Keyword(s):  
Ground State ◽  
Triplet Ground State ◽  
Spectroscopic Evidence

Probing the Ground-State δ Effect of Group 14 Metal Substituents. X-Ray Structures of cis- and trans-4-Trimethylmetal-Substituted Cyclohexyl p-Nitrobenzenesulfonates

1998 ◽  
Vol 51 (7) ◽  
pp. 555 ◽  
Author(s):  
Alison J. Green ◽  
Victor Van ◽  
Jonathan M. White
Keyword(s):  
Low Temperature ◽  
Ground State ◽  
Structural Studies ◽  
Structural Effects ◽  
Group 14 ◽  
X Ray ◽  
Bond Interaction ◽  
Cis And Trans

Accurate low-temperature X-ray structural studies on trans-4-trimethylsilylcyclohexyl p-nitrobenzene- sulfonate (31) and cis- and trans-4-trimethylstannylcyclohexyl p-nitrobenzenesulfonates (32) and (33) failed to demonstrate the presence of any significant structural effects due to a σM-C-σC-C-σ*C-O through-bond interaction between the C–M σ donor orbital and the σ*C-ONs acceptor orbital.

Spectroscopic Evidence for a 3d10 Ground State Electronic Configuration and Ligand Field Inversion in [Cu(CF3)4]1–

2016 ◽  
Vol 138 (6) ◽  
pp. 1922-1931 ◽  
Author(s):  
Richard C. Walroth ◽  
James T. Lukens ◽  
Samantha N. MacMillan ◽  
Kenneth D. Finkelstein ◽  
Kyle M. Lancaster
Keyword(s):  
Ground State ◽  
Electronic Configuration ◽  
Ligand Field ◽  
Spectroscopic Evidence ◽  
Field Inversion
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