Preparation, identification, and crystal structure of a novel hexanuclear iridium–copper cluster complex

Author(s):  
O. M. Abu Salah ◽  
M. I. Bruce ◽  
Melvyn R. Churchill ◽  
Susan A. Bezman
1989 ◽  
Vol 67 (3) ◽  
pp. 551-554 ◽  
Author(s):  
Sydney Brownstein ◽  
Nam Fong Han ◽  
Eric Gabe ◽  
Florence Lee

μ4-Oxo-hexa-μ-chloro-tetrakis{(dimethyl sulfoxide)copper(II)}•dimethyl sulfide, from the reaction of copper metal, dimethyl sulfoxide, and carbon tetrachloride crystallizes as orange crystals in the orthorhombic noncentrosymmetric space group P212121 with a = 10.5820(20), b = 10.5710(20), and c = 28.255(5) Å and Z = 4. The chirality of the individual molecules is attributed to twists of the planes of the sulfur and carbon atoms of the dimethyl sulfoxide ligands relative to the oxygen–copper–oxygen axes. Keywords: crystal structure, copper cluster complex.


1985 ◽  
Vol 4 (10) ◽  
pp. 1898-1900 ◽  
Author(s):  
John R. Shapley ◽  
Wen Yann. Yeh ◽  
Melvyn Rowen. Churchill ◽  
Yong Ji. Li

2014 ◽  
Vol 55 (5) ◽  
pp. 920-922 ◽  
Author(s):  
Ya. M. Gaifulin ◽  
A. I. Smolentsev ◽  
Yu. V. Mironov

Polyhedron ◽  
1984 ◽  
Vol 3 (9-10) ◽  
pp. 1093-1097 ◽  
Author(s):  
Mark J. Freeman ◽  
Anthony D. Miles ◽  
Martin Murray ◽  
A. Guy Orpen ◽  
F.Gordon A. Stone

1986 ◽  
Vol 25 (25) ◽  
pp. 4541-4546 ◽  
Author(s):  
Parimal K. Bharadwaj ◽  
Elizabeth John ◽  
Chuan Liang Xie ◽  
Dechun Zhang ◽  
David N. Hendrickson ◽  
...  

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