A low temperature stopped-flow investigation of manganese(II) complex formation with bipyridyl-type ligands in anhydrous methanol

1972 ◽  
pp. 717 ◽  
Author(s):  
D. J. Benton ◽  
P. Moore
Keyword(s):  
Low Temperature ◽  
Complex Formation ◽  
Anhydrous Methanol ◽  
Stopped Flow ◽  
Flow Investigation

scholarly journals Pressure dependent low temperature kinetics for CN + CH3CN: competition between chemical reaction and van der Waals complex formation

2016 ◽  
Vol 18 (22) ◽  
pp. 15118-15132 ◽  
Author(s):  
Chantal Sleiman ◽  
Sergio González ◽  
Stephen J. Klippenstein ◽  
Dahbia Talbi ◽  
Gisèle El Dib ◽  
...  
Keyword(s):  
Low Temperature ◽  
Complex Formation ◽  
Gas Phase ◽  
Rate Coefficient ◽  
Flow Reactor ◽  
Slow Flow ◽  
Phase Reaction ◽  
Gas Phase Reaction ◽  
Low Temperature Kinetics ◽  
Temperature And Pressure

The gas phase reaction between the CN radical and acetonitrile CH3CN was investigated experimentally with a CRESU apparatus and a slow flow reactor as well as theoretically to explore the temperature and pressure dependence of its rate coefficient from 354 K down to 23 K.

scholarly journals KINETIC STUDY ON ANIONIC σ-COMPLEX FORMATION BETWEEN 2,4,6-TRINITROANISOLE AND METHOXIDE ION BY HIGH PRESSURE STOPPED-FLOW METHOD

1979 ◽  
Vol 8 (6) ◽  
pp. 671-674 ◽  
Author(s):  
Noboru Takisawa ◽  
Muneo Sasaki ◽  
Fujitsugu Amita ◽  
Jiro Osugi
Keyword(s):  
High Pressure ◽  
Complex Formation ◽  
Kinetic Study ◽  
Stopped Flow ◽  
Flow Method ◽  
Methoxide Ion

Kinetics and Equilibrium of Binding of Fe3+ by a Fulvic Acid: A Study by Stopped Flow Methods

1975 ◽  
Vol 53 (20) ◽  
pp. 2979-2984 ◽  
Author(s):  
Cooper H. Langford ◽  
Tahir R. Khan
Keyword(s):  
Ionic Strength ◽  
Complex Formation ◽  
Fulvic Acid ◽  
Metal Ion ◽  
Equilibrium Constants ◽  
Acid Dissociation ◽  
Stopped Flow ◽  
Solution Ph ◽  
Sulfosalicylic Acid ◽  
Flow Measurements

The first report of a rate of binding of a metal ion (Fe3+) by a soluble fulvic acid is derived from stopped flow measurements. The rate of complex formation is normal in Wilkins' sense and similar to that for sulfosalicylic acid. Dissociation is slow (t1/2 > 10 s). The binding of Fe3+ by the fulvic acid in acid solution, pH = 1–2.5, was investigated by kinetic analysis in which the reaction of free Fe3+ with sulfosalicylic acid was followed by stopped flow spectrophotometry on a time scale short compared to release of Fe3+ by fulvic acid. Conditional equilibrium constants found were 1.5 ± 0.3 × 104 at pH = 1.5 and 2.5, and 2.8 ± 0.3 × 103 at pH = 1.0 at 25 °C (ionic strength 0.1).

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