Mechanisms of multi-shape memory effects and associated energy release in shape memory polymers

Soft Matter ◽  
2012 ◽  
Vol 8 (20) ◽  
pp. 5687 ◽  
Author(s):  
Kai Yu ◽  
Tao Xie ◽  
Jinsong Leng ◽  
Yifu Ding ◽  
H. Jerry Qi
RSC Advances ◽  
2021 ◽  
Vol 11 (32) ◽  
pp. 19616-19622
Author(s):  
Wenbing Li ◽  
Junhao Liu ◽  
Wanting Wei ◽  
Kun Qian

Shape memory polymers can provide excellent bonding property because of their shape memory effects. This paper proposes an adhesive unit that is capable of repeatable smart adhesion and exhibits reversible adhesion under heating.


2013 ◽  
Vol 22 (9) ◽  
pp. 093001 ◽  
Author(s):  
Harper Meng ◽  
Habib Mohamadian ◽  
Michael Stubblefield ◽  
Dwayne Jerro ◽  
Samuel Ibekwe ◽  
...  

Micromachines ◽  
2021 ◽  
Vol 12 (7) ◽  
pp. 833
Author(s):  
Zepeng He ◽  
Yang Shi ◽  
Xiangchao Feng ◽  
Zhen Li ◽  
Yan Zhang ◽  
...  

Shape memory polymers (SMPs) have been applied in aerospace engineering as deployable space structures. In this work, the coupled finite element method (FEM) was established based on the generalized Maxwell model and the time–temperature equivalence principle (TTEP). The thermodynamic behavior and shape memory effects of a single-arm deployment structure (F-DS) and four-arm deployment structure (F-DS) based on SMPs were analyzed using the coupled FEM. Good consistency was obtained between the experimental data and simulation data for the tensile and S-DS recovery forces, verifying that the coupled FEM can accurately and reliably describe the thermodynamic behavior and shape memory effects of the SMP structure. The step-by-step driving structure is suitable for use as a large-scale deployment structure in space. This coupled FEM provides a new direction for future research on epoxy SMPs.


RSC Advances ◽  
2016 ◽  
Vol 6 (13) ◽  
pp. 10233-10241 ◽  
Author(s):  
Qiwei Zhang ◽  
Hongqiu Wei ◽  
Yanju Liu ◽  
Jinsong Leng ◽  
Shanyi Du

A series of bismaleimide based triple shape memory polymers with heterogeneous crosslinking structures were synthesized, and their shape memory behaviours are characterized.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Wang Zhang ◽  
Hao Wang ◽  
Hongtao Wang ◽  
John You En Chan ◽  
Hailong Liu ◽  
...  

AbstractFour-dimensional (4D) printing of shape memory polymer (SMP) imparts time responsive properties to 3D structures. Here, we explore 4D printing of a SMP in the submicron length scale, extending its applications to nanophononics. We report a new SMP photoresist based on Vero Clear achieving print features at a resolution of ~300 nm half pitch using two-photon polymerization lithography (TPL). Prints consisting of grids with size-tunable multi-colours enabled the study of shape memory effects to achieve large visual shifts through nanoscale structure deformation. As the nanostructures are flattened, the colours and printed information become invisible. Remarkably, the shape memory effect recovers the original surface morphology of the nanostructures along with its structural colour within seconds of heating above its glass transition temperature. The high-resolution printing and excellent reversibility in both microtopography and optical properties promises a platform for temperature-sensitive labels, information hiding for anti-counterfeiting, and tunable photonic devices.


2015 ◽  
Vol 3 (26) ◽  
pp. 13953-13961 ◽  
Author(s):  
Li Yu ◽  
Qian Wang ◽  
Jian Sun ◽  
Chenyue Li ◽  
Cheng Zou ◽  
...  

Tuneable shape-memory effects can be achieved in a wavelength-selective multicomposite.


2012 ◽  
Vol 27 (22) ◽  
pp. 2837-2843 ◽  
Author(s):  
S.M. Kang ◽  
M.J. Kim ◽  
S.H. Kwon ◽  
H. Park ◽  
H.M. Jeong ◽  
...  

Abstract


2015 ◽  
Vol 2015 ◽  
pp. 1-8 ◽  
Author(s):  
Xixi Li ◽  
Yaofeng Zhu ◽  
Yubing Dong ◽  
Meng Liu ◽  
Qingqing Ni ◽  
...  

Triple-shape memory epoxy composites with bilayer structures of well-separated glass transition temperatures have been successfully prepared. The different glass transition temperatures of the epoxy composites were obtained by physically incorporating various amounts of nanosilica particles, which were introduced into the epoxy by utilizing polyethylene glycol. A scanning electron microscope and a transmission electron microscope were used to analyze the dispersibility of the nanosilica particles. The effects of nanosilica particles on the mechanical properties as well as on the dual-shape memory effects (DSME) and triple-shape memory effects (TSME) of the nanocomposites were studied. The nanosilica particles were homogenously dispersed in the matrix and well incorporated into the epoxy matrix. The resulting nanocomposites exhibited excellent TSME, and their shape fixity properties were significantly improved by nanosilica particles.


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