Self-assembly of alkoxysilanized humic substances into multidomain adlayers at the water–solid interface: linking surface morphology to the molecular structure of the adsorbate

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2D self-assembly of a novel π-conjugated oligomer terminated by two uracil units is solvent dependent and involves multiple intermolecular H-bonds.


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Linear oligomeric [2-(carboxymethylthio)ethylsilsesquioxanes] (LPSQ-COOH) adsorb spontaneously on muscovite mica and form smooth, well-ordered lamellar structures at the liquid–solid interface.


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Asymmetric dynamics in fundamental adsorption and desorption steps drive self-assembly at solution/solid interface.


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