Concertedness in proton-coupled electron transfer cleavages of carbon–metal bonds illustrated by the reduction of an alkyl cobalt porphyrin

2013 ◽  
Vol 4 (2) ◽  
pp. 819-823 ◽  
Author(s):  
Cyrille Costentin ◽  
Guillaume Passard ◽  
Marc Robert ◽  
Jean-Michel Savéant
Keyword(s):  
Electron Transfer ◽  
Cobalt Porphyrin ◽  
Proton Coupled Electron Transfer ◽  
Metal Bonds

scholarly journals Proton-coupled electron transfer in the electrocatalysis of CO2 reduction: prediction of sequential vs. concerted pathways using DFT

2017 ◽  
Vol 8 (1) ◽  
pp. 458-465 ◽  
Author(s):  
Adrien J. Göttle ◽  
Marc T. M. Koper
Keyword(s):  
Electron Transfer ◽  
Co2 Reduction ◽  
Electrocatalytic Reduction ◽  
Cobalt Porphyrin ◽  
Proton Coupled Electron Transfer ◽  
Detailed Picture

We provide a complete and computationally detailed picture of the mechanism of the initial stages of the electrocatalytic reduction of CO2 in water catalysed by cobalt porphyrin complexes.

scholarly journals Electron–Nuclear Dynamics Accompanying Proton-Coupled Electron Transfer

2021 ◽  
Vol 143 (8) ◽  
pp. 3104-3112
Author(s):  
Yusuke Yoneda ◽  
S. Jimena Mora ◽  
James Shee ◽  
Brian L. Wadsworth ◽  
Eric A. Arsenault ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Nuclear Dynamics ◽  
Proton Coupled Electron Transfer

Facile proton-coupled electron transfer enabled by coordination-induced E–H bond weakening to boron

2021 ◽  
Author(s):  
Anthony Wong ◽  
Arunavo Chakraborty ◽  
Deependra Bawari ◽  
Guang Wu ◽  
Roman Dobrovetsky ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Proton Coupled Electron Transfer

Coordination induced bond weakening (CIBW) leads to facile PCET at various E–H bonds.

Hydroarylation of Activated Alkenes Enabled by Proton-Coupled Electron Transfer

ACS Catalysis ◽  
2021 ◽  
pp. 4422-4429
Author(s):  
Zhaosheng Liu ◽  
Shuai Zhong ◽  
Xiaochen Ji ◽  
Guo-Jun Deng ◽  
Huawen Huang
Keyword(s):  
Electron Transfer ◽  
Proton Coupled Electron Transfer
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