Pair distribution function-derived mechanism of a single-crystal to disordered to single-crystal transformation in a hemilabile metal–organic framework

2012 ◽  
Vol 3 (8) ◽  
pp. 2559 ◽  
Author(s):  
Phoebe K. Allan ◽  
Karena W. Chapman ◽  
Peter J. Chupas ◽  
Joseph A. Hriljac ◽  
Catherine L. Renouf ◽  
...  
Keyword(s):  
Distribution Function ◽  
Single Crystal ◽  
Pair Distribution Function ◽  
Metal Organic Framework ◽  
Crystal Transformation ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Stepwise collapse of a giant pore metal–organic framework

2021 ◽  
Vol 50 (14) ◽  
pp. 5011-5022 ◽  
Author(s):  
Adam F. Sapnik ◽  
Duncan N. Johnstone ◽  
Sean M. Collins ◽  
Giorgio Divitini ◽  
Alice M. Bumstead ◽  
...  
Keyword(s):  
Distribution Function ◽  
Hierarchical Structure ◽  
Pair Distribution Function ◽  
Function Analysis ◽  
Metal Organic Framework ◽  
Defect Engineering ◽  
Structural Collapse ◽  
The Hierarchical Structure ◽  
Metal Organic ◽  
Organic Framework

Defect engineering is used to augment the porosity of MIL-100. Incorporation of defects leads to structural collapse and ultimately causes amorphisation. Pair distribution function analysis reveals a stepwise collapse of the hierarchical structure.

Solvent‐Vapor‐Induced Reversible Single‐Crystal‐to‐Single‐Crystal Transformation of a Triphosphaazatriangulene‐Based Metal–Organic Framework

2019 ◽  
Vol 59 (4) ◽  
pp. 1435-1439 ◽  
Author(s):  
Soichiro Nakatsuka ◽  
Yusuke Watanabe ◽  
Yoshinobu Kamakura ◽  
Satoshi Horike ◽  
Daisuke Tanaka ◽  
...  
Keyword(s):  
Single Crystal ◽  
Metal Organic Framework ◽  
Solvent Vapor ◽  
Crystal Transformation ◽  
Metal Organic ◽  
Organic Framework

Solvent‐Vapor‐Induced Reversible Single‐Crystal‐to‐Single‐Crystal Transformation of a Triphosphaazatriangulene‐Based Metal–Organic Framework

2019 ◽  
Vol 132 (4) ◽  
pp. 1451-1455 ◽  
Author(s):  
Soichiro Nakatsuka ◽  
Yusuke Watanabe ◽  
Yoshinobu Kamakura ◽  
Satoshi Horike ◽  
Daisuke Tanaka ◽  
...  
Keyword(s):  
Single Crystal ◽  
Metal Organic Framework ◽  
Solvent Vapor ◽  
Crystal Transformation ◽  
Metal Organic ◽  
Organic Framework

Applications of pair distribution function analyses to the emerging field of non-ideal metal–organic framework materials

Nanoscale ◽  
2020 ◽  
Vol 12 (29) ◽  
pp. 15577-15587 ◽  
Author(s):  
Celia Castillo-Blas ◽  
José María Moreno ◽  
Ignacio Romero-Muñiz ◽  
Ana E. Platero-Prats
Keyword(s):  
Distribution Function ◽  
Pair Distribution Function ◽  
Metal Organic Framework ◽  
Framework Materials ◽  
Metal Organic ◽  
Organic Framework

Pair distribution function, PDF, analyses are emerging as a powerful tool to characterize non-ideal metal–organic framework (MOF) materials with compromised ordering.

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