Mixed-ligand benzaldehyde thiosemicarbazone complexes of palladium containing N,O-donor ancillary ligands. Syntheses, structures, and catalytic application in C–C and C–N coupling reactions

RSC Advances ◽  
2012 ◽  
Vol 2 (31) ◽  
pp. 11751 ◽  
Author(s):  
Jayita Dutta ◽  
Sayanti Datta ◽  
Dipravath Kumar Seth ◽  
Samaresh Bhattacharya
Keyword(s):  
Mixed Ligand ◽  
Coupling Reactions ◽  
Ancillary Ligands ◽  
Catalytic Application ◽  
Thiosemicarbazone Complexes ◽  
Benzaldehyde Thiosemicarbazone

Mixed-Ligand Metal–Organic Framework for Two-Photon Responsive Photocatalytic C–N and C–C Coupling Reactions

ACS Catalysis ◽  
2018 ◽  
Vol 9 (1) ◽  
pp. 422-430 ◽  
Author(s):  
Hanning Li ◽  
Yang Yang ◽  
Cheng He ◽  
Le Zeng ◽  
Chunying Duan
Keyword(s):  
Metal Organic Framework ◽  
Mixed Ligand ◽  
Coupling Reactions ◽  
Two Photon ◽  
Metal Organic ◽  
Organic Framework

Facile Synthesis of Mesoporous Magnetic Nanocomposites and their Catalytic Application in Carbon-Carbon Coupling Reactions

ChemCatChem ◽  
2010 ◽  
Vol 2 (12) ◽  
pp. 1543-1547 ◽  
Author(s):  
Sankaranarayanapillai Shylesh ◽  
Lei Wang ◽  
Serhiy Demeshko ◽  
Werner R. Thiel
Keyword(s):  
Magnetic Nanocomposites ◽  
Coupling Reactions ◽  
Facile Synthesis ◽  
Catalytic Application

scholarly journals Synthesis and Characterization of New Palladium(II) Thiosemicarbazone Complexes and Their Cytotoxic Activity against Various Human Tumor Cell Lines

2013 ◽  
Vol 2013 ◽  
pp. 1-12 ◽  
Author(s):  
Wilfredo Hernández ◽  
Juan Paz ◽  
Fernando Carrasco ◽  
Abraham Vaisberg ◽  
Evgenia Spodine ◽  
...  
Keyword(s):  
Tumor Cell ◽  
Cytotoxic Activity ◽  
Cell Lines ◽  
Human Tumor ◽  
Tumor Cell Lines ◽  
Human Tumor Cell ◽  
Human Tumor Cell Lines ◽  
Thiosemicarbazone Complexes ◽  
Benzaldehyde Thiosemicarbazone

The palladium(II) bis-chelate complexes of the type [Pd(TSC1-5)2] (6–10), with their corresponding ligands 4-phenyl-1-(acetone)-thiosemicarbazone, HTSC1(1), 4-phenyl-1-(2′-chloro-benzaldehyde)-thiosemicarbazone, HTSC2(2), 4-phenyl-1-(3′-hydroxy-benzaldehyde)-thiosemicarbazone, HTSC3(3), 4-phenyl-1-(2′-naphthaldehyde)-thiosemicarbazone, HTSC4(4), and 4-phenyl-1-(1′-nitro-2′-naphthaldehyde)-thiosemicarbazone, HTSC5(5), were synthesized and characterized by elemental analysis and spectroscopic techniques (IR and1H- and13C-NMR). The molecular structure of HTSC3, HTSC4, and [Pd(TSC1)2] (6) have been determined by single crystal X-ray crystallography. Complex6shows a square planar geometry with two deprotonated ligands coordinated toPdIIthrough the azomethine nitrogen and thione sulfur atoms in acisarrangement. Thein vitrocytotoxic activity measurements indicate that the palladium(II) complexes (IC50=0.01–9.87 μM) exhibited higher antiproliferative activity than their free ligands (IC50=23.48–70.86 and >250 μM) against different types of human tumor cell lines. Among all the studied palladium(II) complexes, the [Pd(TSC3)2] (8) complex exhibited high antitumor activity on the DU145 prostate carcinoma and K562 chronic myelogenous leukemia cells, with low values of the inhibitory concentration (0.01 and 0.02 μM, resp.).Corrigendum to “Synthesis and Characterization of New Palladium(II) Thiosemicarbazone Complexes and Their Cytotoxic Activity against Various Human Tumor Cell Lines”

Synthesis of Water-Dispersible Pd Nanoparticles Using a Novel Oxacalixarene Derivative and their Catalytic Application in C–C Coupling Reactions

2016 ◽  
Vol 146 (8) ◽  
pp. 1581-1590 ◽  
Author(s):  
Viren Mehta ◽  
Manthan Panchal ◽  
Anita Kongor ◽  
Urvi Panchal ◽  
V. K. Jain
Keyword(s):  
Pd Nanoparticles ◽  
Coupling Reactions ◽  
Water Dispersible ◽  
Catalytic Application

scholarly journals Syntheses, structures and efficient catalysis for C–C coupling of some benzaldehyde thiosemicarbazone complexes of palladium

2011 ◽  
Vol 344 (1-2) ◽  
pp. 62-73 ◽  
Author(s):  
Piyali Paul ◽  
Sayanti Datta ◽  
Sarmistha Halder ◽  
Rama Acharyya ◽  
Falguni Basuli ◽  
...  
Keyword(s):  
Thiosemicarbazone Complexes ◽  
Benzaldehyde Thiosemicarbazone

Mixed-ligand nickel(II) thiosemicarbazone complexes: Synthesis, characterization and biological evaluation

Polyhedron ◽  
2013 ◽  
Vol 50 (1) ◽  
pp. 354-363 ◽  
Author(s):  
Saswati ◽  
Rupam Dinda ◽  
Carla S. Schmiesing ◽  
Ekkehard Sinn ◽  
Yogesh P. Patil ◽  
...  
Keyword(s):  
Biological Evaluation ◽  
Mixed Ligand ◽  
Thiosemicarbazone Complexes
Sign in / Sign up

Export Citation Format

Share Document