Recent advances of sodium borohydride reduction in coal water slurry desulfurization: integration of chemical and electrochemical reduction

RSC Advances ◽  
2012 ◽  
Vol 2 (24) ◽  
pp. 8867 ◽  
Author(s):  
Yafei Shen ◽  
Xunyue Liu ◽  
Tonghua Sun ◽  
Jinping Jia
Keyword(s):  
Electrochemical Reduction ◽  
Sodium Borohydride ◽  
Borohydride Reduction ◽  
Water Slurry ◽  
Recent Advances ◽  
Coal Water Slurry ◽  
Sodium Borohydride Reduction

Electrochemical Synthesis of Deuterio Organic Compounds. I. Electrochemical Reduction of 1-Halonaphthalenes and Synthesis of 1-Chloro-4-methylnaphthalene

1974 ◽  
Vol 52 (3) ◽  
pp. 376-380 ◽  
Author(s):  
Roger N. Renaud
Keyword(s):  
Electrochemical Reduction ◽  
Organic Compounds ◽  
Sodium Borohydride ◽  
Deuterium Content ◽  
Borohydride Reduction ◽  
Deuterated Water ◽  
Chloro Derivative ◽  
Simultaneous Transfer ◽  
Sodium Borohydride Reduction ◽  
Methyl Naphthalene

Electrochemical reduction of 1-chloro-, 1-bromo-, 1-iodo-, 1-chloro-4-methyl-, and 1-bromo-4-methyl naphthalene was done in presence of deuterated water. The deuterium content of the naphthalene obtained reveals that the mechanism for the bromo and the iodo derivatives might involve either a simultaneous transfer of two electrons or an organometallic intermediate, while reduction of the chloro derivative might proceed at least partially via a radical intermediate.The synthesis of 1-chloro-4-methylnaphthalene from 1-chloro-4-chloromethylnaphthalene was achieved either by selective sodium borohydride reduction or by selective electrochemical reduction.

1,2-Benzothiazines. II. The Preparation and Sodium Borohydride Reduction of 3-Acyl-2H-1,2-benzothiazin-4(3H)-one 1,1-Dioxides1

1965 ◽  
Vol 30 (7) ◽  
pp. 2241-2246 ◽  
Author(s):  
Harold Zinnes ◽  
Roger A. Comes ◽  
Francis R. Zuleski ◽  
Albert N. Caro ◽  
John Shavel
Keyword(s):  
Sodium Borohydride ◽  
Borohydride Reduction ◽  
Sodium Borohydride Reduction
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