Functionalized linear low-density polyethylene by ring-opening metathesis polymerization

2013 ◽  
Vol 4 (4) ◽  
pp. 1193-1198 ◽  
Author(s):  
Shingo Kobayashi ◽  
Hyunwoo Kim ◽  
Christopher W. Macosko ◽  
Marc A. Hillmyer
Keyword(s):  
Ring Opening ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Linear Low Density Polyethylene ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization

Precision ethylene-styrene copolymers through the ring opening metathesis polymerization of 3-phenyl cyclododecenes

2021 ◽  
Author(s):  
Sebla Onbulak ◽  
Marc A. Hillmyer
Keyword(s):  
Ring Opening ◽  
Side Chain ◽  
Low Density ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization ◽  
Styrene Copolymers

Precision polyolefin copolymers were synthesized by ROMP of phenyl-substituted cyclododecenes. Hydrogenation of the polydodecenamers afforded linear low density polyethylenes with a phenyl side chain every twelve backbone carbons.

scholarly journals Exploration of the versatility of ring opening metathesis polymerization: an approach for gaining access to low density polymeric aerogels

RSC Advances ◽  
2012 ◽  
Vol 2 (23) ◽  
pp. 8672 ◽  
Author(s):  
Sung Ho Kim ◽  
Marcus A. Worsley ◽  
Carlos A. Valdez ◽  
Swanee J. Shin ◽  
Christoph Dawedeit ◽  
...  
Keyword(s):  
Ring Opening ◽  
Low Density ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization

Model Linear Low Density Polyethylenes from the ROMP of 5-Hexylcyclooct-1-ene

2010 ◽  
Vol 63 (8) ◽  
pp. 1201 ◽  
Author(s):  
Shingo Kobayashi ◽  
Christopher W. Macosko ◽  
Marc A. Hillmyer
Keyword(s):  
Differential Scanning Calorimetry ◽  
Catalytic Hydrogenation ◽  
Ring Opening ◽  
Branched Polymers ◽  
Low Density Polyethylene ◽  
Heat Of Fusion ◽  
Low Density ◽  
Linear Low Density Polyethylene ◽  
Scanning Calorimetry ◽  
Feed Composition

Model hexyl-branched linear low density polyethylene (C8-LLDPE) samples were synthesized by the ring-opening metathesis copolymerization (ROMP) of the 5-hexylcyclooct-1-ene (1) and cyclooctadiene (COD), followed by catalytic hydrogenation. The ROMP of 1 and copolymerization of 1 and COD using the Grubbs second generation catalyst (G2) afford polymers with the number of hexyl branches based on the feed composition. The resulting hexyl-branched polymers, poly(1) and poly(1-stat-COD), were completely converted into model C8-LLDPE samples by catalytic hydrogenation. The C8-LLDPE samples exhibit the expected reduction in density on branching content. The melting temperature (Tm), crystallization temperature (Tc), and heat of fusion/crystallization (ΔHm/ΔHc) of these materials were studied by differential scanning calorimetry.

Synthesis and Purification of Tunable High Tg Electro-Optical Polymers by Ring Opening Metathesis Polymerization

2011 ◽  
Author(s):  
Robert H. Lambeth ◽  
Joseph M. Dougherty ◽  
Joshua A. Orlicki ◽  
Adam M. Rawlett ◽  
Robert C. Hoffman ◽  
...  
Keyword(s):  
Ring Opening ◽  
Optical Polymers ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization

Surface modification of carbon fibres using ring-opening metathesis polymerization

2021 ◽  
Vol 145 ◽  
pp. 106374
Author(s):  
David J. Hayne ◽  
Filip Stojcevski ◽  
Daniel B. Knorr ◽  
Ngon T. Tran ◽  
Luke C. Henderson
Keyword(s):  
Surface Modification ◽  
Ring Opening ◽  
Carbon Fibres ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization
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