Novel CeO2 yolk–shell structures loaded with tiny Au nanoparticles for superior catalytic reduction of p-nitrophenol

Nanoscale ◽  
2012 ◽  
Vol 4 (21) ◽  
pp. 6835 ◽  
Author(s):  
Cong-Min Fan ◽  
Lin-Fei Zhang ◽  
Sha-Sha Wang ◽  
Dong-Hong Wang ◽  
Li-Qiang Lu ◽  
...  
2004 ◽  
Vol 397 (1-3) ◽  
pp. 128-132 ◽  
Author(s):  
Xing-bin Yan ◽  
Tao Xu ◽  
Shan Xu ◽  
Gang Chen ◽  
Qun-ji Xue ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (10) ◽  
pp. 7554-7558 ◽  
Author(s):  
Hyunje Woo ◽  
Ji Woong Kim ◽  
Miran Kim ◽  
Sungkyun Park ◽  
Kang Hyun Park

A one-pot hydrothermal synthesis approach was developed to prepare FeSO4·(H2O)–graphene oxide (GO) nanosheets. Au nanoparticles were immobilized onto this support, giving Au/Fe2O3–GO nanocomposites.


2020 ◽  
Vol 01 ◽  
Author(s):  
Huiying Wu ◽  
Feng Liang

Background: Porous Au nanomaterials show great potential in the fields of biomedicine, drug delivery and catalysis for the merits of low density, large void space and large specific surface area. The preparation of porous Au nanomaterials is usually carried out by using a hard-templating method which is cumbersome. Methods: Dandelion-like porous Au nanoparticles were synthesized through a soft-templating method in our work. The synthesized porous Au nanoparticles were characterized via transmission electron microscopy (TEM), X-ray diffraction (XRD), energy-dispersive X-ray (EDX) and cyclic voltammetry (CV). The reduction of nitrophenol was carried out to evaluate the catalytic behavior of porous Au nanoparticles. Results: Porous Au nanoparticles prepared were in uniform size (47.9±6.4 nm) and the morphology could be regulated by adjusting the molar ratio of reactants. The apparent rate constant (kapp) value of reducing nitrophenol catalyzed by porous Au nanoparticles was higher than Au nanospheres and nanobranches in similar size. It could be attributed to the large amount of active sites and high proportion of high-order crystal faces proved by CV and XRD. Conclusion: We developed a facile and reproducible method for synthesizing porous Au nanoparticles. The morphology of porous Au nanoparticles can be ajusted by changing the molar ratio of reactants. Porous Au nanoparticles we prepared behaved better in catalysis compared with Au nanospheres and Au nanobranches.


2018 ◽  
Vol 14 (2) ◽  
pp. 82-94 ◽  
Author(s):  
Nelson Duran ◽  
Amedea B. Seabra

Background: Bimetallic silver-gold nanoparticles (Ag/Au NPs) with different structures have recently gained scientific attention due to their new and superior properties in comparison with metallic NPs made from a single metal. Ag/Au NPs (alloy or core-shell structures) have been applied to several biomedical, technological, and environmental applications. The potential applications of Ag/Au NPs are widespread yet poorly investigated in comparison with monometallic NPs. Besides traditional chemical and physical routes to synthesize bimetallic Ag/Au NPs, biogenic protocols are considered cost-effective, simple, and environmentally friendly. Despite their simplicity, biogenic routes to synthesize Ag/Au NPs are less explored than traditional synthetic protocols. Methods: In this context, we present a review and discuss recent progress in the preparation of bimetallic Ag/Au NPs with different morphologies, structures, and size distributions using biogenic synthetic protocols. Results: Biogenic synthesis using plant extracts, algae, bacteria, fungi, and other biological agents are presented and discussed. The characterization and potential applications of biogenically synthesized Ag/Au NPs in the different areas of medicine and biological applications, such as antibacterial, anticandidal, anticancer, antidiabetes, and as sensors for clinical diagnosis are presented and discussed. Conclusion: Finally, challenges and drawbacks in the biological routes for the preparation of Ag/Au NPs for industrial applications are also discussed.


2015 ◽  
Vol 39 (11) ◽  
pp. 8623-8629 ◽  
Author(s):  
Zhengping Dong ◽  
Guiqin Yu ◽  
Xuanduong Le

Au nanoparticles were immobilized on magnetic fibrous silica microspheres as highly active and recyclable nanocatalysts for the catalytic reduction of 4-nitrophenol to 4-aminophenol.


RSC Advances ◽  
2017 ◽  
Vol 7 (72) ◽  
pp. 45545-45551 ◽  
Author(s):  
Shili Liu ◽  
Aori Qileng ◽  
Junying Huang ◽  
Qiongzhi Gao ◽  
Yingju Liu

The in situ assembly of Au nanoparticles on Fe3O4@PDA showed excellent recyclability and good stability for the catalytic reduction of 4-nitrophenol.


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