Controlled growth of ZnO/Zn1−xPbxSe core–shell nanowires and their interfacial electronic energy alignment

Nanoscale ◽  
2012 ◽  
Vol 4 (10) ◽  
pp. 3154 ◽  
Author(s):  
Z. H. Chen ◽  
S. Y. Yeung ◽  
H. Li ◽  
J. C. Qian ◽  
W. J. Zhang ◽  
...  
Nano Research ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 157-164
Author(s):  
H. Aruni Fonseka ◽  
Yunyan Zhang ◽  
James A. Gott ◽  
Richard Beanland ◽  
Huiyun Liu ◽  
...  

AbstractHighly faceted geometries such as nanowires are prone to form self-formed features, especially those that are driven by segregation. Understanding these features is important in preventing their formation, understanding their effects on nanowire properties, or engineering them for applications. Single elemental segregation lines that run along the radii of the hexagonal cross-section have been a common observation in alloy semiconductor nanowires. Here, in GaAsP nanowires, two additional P rich bands are formed on either side of the primary band, resulting in a total of three segregation bands in the vicinity of three of the alternating radii. These bands are less intense than the primary band and their formation can be attributed to the inclined nanofacets that form in the vicinity of the vertices. The formation of the secondary bands requires a higher composition of P in the shell, and to be grown under conditions that increase the diffusivity difference between As and P. Furthermore, it is observed that the primary band can split into two narrow and parallel bands. This can take place in all six radii, making the cross sections to have up to a maximum of 18 radial segregation bands. With controlled growth, these features could be exploited to assemble multiple different quantum structures in a new dimension (circumferential direction) within nanowires.


2019 ◽  
Author(s):  
Jiajia Tao ◽  
Hong-Ping Ma ◽  
Kaiping Yuan ◽  
Yang Gu ◽  
Jianwei Lian ◽  
...  

<div>As a promising oxygen evolution reaction semiconductor, TiO2 has been extensively investigated for solar photoelectrochemical water splitting. Here, a highly efficient and stable strategy for rationally preparing GaON cocatalysts on TiO2 by atomic layer deposition is demonstrated, which we show significantly enhances the</div><div>photoelectrochemical performance compared to TiO2-based photoanodes. For TiO2@20 nm-GaON core-shell nanowires a photocurrent density up to 1.10 mA cm-2 (1.23 V vs RHE) under AM 1.5 G irradiation (100 mW cm-2) has been achieved, which is 14 times higher than that of TiO2 NWs. Furthermore, the oxygen vacancy formation on GaON as well as the band gap matching with TiO2 not only provides more active sites for water oxidation but also enhances light absorption to promote interfacial charge separation and migration. Density functional theory studies of model systems of GaON-modified TiO2 confirm the band gap reduction, high reducibility and ability to activate water. The highly efficient and stable systems of TiO2@GaON core-shell nanowires provide a deeper understanding and universal strategy for enhancing photoelectrochemical performance of photoanodes now available. </div>


2021 ◽  
Vol 5 (7) ◽  
pp. 2100185
Author(s):  
Soomin Son ◽  
Jaemin Park ◽  
Sucheol Ju ◽  
Daihong Huh ◽  
Junho Jun ◽  
...  

2019 ◽  
Vol 30 (30) ◽  
pp. 304001 ◽  
Author(s):  
C Himwas ◽  
S Collin ◽  
H-L Chen ◽  
G Patriarche ◽  
F Oehler ◽  
...  
Keyword(s):  

Nano Research ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 61-66
Author(s):  
Alexandre Bucamp ◽  
Christophe Coinon ◽  
David Troadec ◽  
Sylvie Lepilliet ◽  
Gilles Patriarche ◽  
...  

AIP Advances ◽  
2013 ◽  
Vol 3 (6) ◽  
pp. 062114 ◽  
Author(s):  
P. Sangeetha ◽  
K. Jeganathan ◽  
V. Ramakrishnan
Keyword(s):  

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