Organocatalytic upgrading of the key biorefining building block by a catalytic ionic liquid and N-heterocyclic carbenes

2012 ◽  
Vol 14 (10) ◽  
pp. 2738 ◽  
Author(s):  
Dajiang (D. J.) Liu ◽  
Yuetao Zhang ◽  
Eugene Y.-X. Chen
Keyword(s):  
Ionic Liquid ◽  
Building Block ◽  
Heterocyclic Carbenes

ChemInform Abstract: Ionic Liquid Mediated Formation of 5-Hydroxymethylfurfural - A Promising Biomass-Derived Building Block

ChemInform ◽  
2011 ◽  
Vol 42 (20) ◽  
pp. no-no ◽  
Author(s):  
Malgorzata E. Zakrzewska ◽  
Ewa Bogel-Lukasik ◽  
Rafal Bogel-Lukasik
Keyword(s):  
Ionic Liquid ◽  
Building Block

scholarly journals Nanostructured thermosets from ionic liquid building block–epoxy prepolymer mixtures

RSC Advances ◽  
2014 ◽  
Vol 4 (53) ◽  
pp. 28099-28106 ◽  
Author(s):  
Sébastien Livi ◽  
Adriana A. Silva ◽  
Yohann Thimont ◽  
Thi Khanh Ly Nguyen ◽  
Bluma G. Soares ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Building Block ◽  
Phosphonium Ionic Liquid

TEM micrographs of the epoxy–IL cured systems with 30 wt% of phosphonium ionic liquid.

Umpolung reactions in an ionic liquid catalyzed by electrogenerated N-heterocyclic carbenes. Synthesis of saturated esters from activated α,β-unsaturated aldehydes

2012 ◽  
Vol 48 (43) ◽  
pp. 5361 ◽  
Author(s):  
Marta Feroci ◽  
Isabella Chiarotto ◽  
Monica Orsini ◽  
Romina Pelagalli ◽  
Achille Inesi
Keyword(s):  
Ionic Liquid ◽  
Heterocyclic Carbenes ◽  
Unsaturated Aldehydes

Ionic Liquid-Catalyzed C–S Bond Construction using CO2 as a C1 Building Block under Mild Conditions: A Metal-Free Route to Synthesis of Benzothiazoles

ACS Catalysis ◽  
2015 ◽  
Vol 5 (11) ◽  
pp. 6648-6652 ◽  
Author(s):  
Xiang Gao ◽  
Bo Yu ◽  
Zhenzhen Yang ◽  
Yanfei Zhao ◽  
Hongye Zhang ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Building Block ◽  
Metal Free ◽  
Mild Conditions

scholarly journals Facile synthesis of reversibly crosslinked poly(ionic liquid)-type gels: Recyclable supports for organocatalysis by N-heterocyclic carbenes

2018 ◽  
Vol 107 ◽  
pp. 82-88 ◽  
Author(s):  
Sofiem Garmendia ◽  
Romain Lambert ◽  
Anne-Laure Wirotius ◽  
Joan Vignolle ◽  
Andrew P. Dove ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Heterocyclic Carbenes ◽  
Facile Synthesis ◽  
Liquid Type ◽  
Poly Ionic Liquid

scholarly journals Nickel and palladium complexes of enolatefunctionalised N-heterocyclic carbenes

2010 ◽  
Vol 8 (5) ◽  
pp. 992-998 ◽  
Author(s):  
Saravanakumar Shanmuganathan ◽  
Olaf Kühl ◽  
Peter Jones ◽  
Joachim Heinicke
Keyword(s):  
Crystal Structure ◽  
Ionic Liquid ◽  
Nickel Complexes ◽  
Palladium Complexes ◽  
Heterocyclic Carbenes ◽  
Ethylene Oligomerization ◽  
Pure Form ◽  
Chloride Crystal ◽  
In Situ Techniques

AbstractThe reaction of chloroethyltrimethylsilylether with 1-methylimidazole furnishes an ionic liquid that undergoes methanolysis to crystalline 2-hydroxyethylimidazolium chloride (crystal structure presented). Conversion to defined hydroxyethylimidazol-2-ylidene nickel complexes failed, but was accomplished with 1-methyl-3-acetophenyl-imidazolium bromide. The bis(NHC⋂O−) nickel(II) chelate is formed, rather than a methallylnickel monochelate, but with nickelocene a monochelate NiCp complex was detected. The bulky 1-(2,6-diisopropylphenyl)-3-(2’-phenyl-enolato)-imidazol-2-ylidene allylpalladium chloride was obtained in pure form. Attempts to generate catalysts for ethylene oligomerization by in situ techniques have failed so far whereas P⋂O− ligands, comparable by the P-C diagonal relationship, provide active catalysts.

NEW AMINE FUNCTIONAL IONIC LIQUID AS BUILDING BLOCK IN NANOTECHNOLOGY

NANO ◽  
2007 ◽  
Vol 02 (03) ◽  
pp. 169-173 ◽  
Author(s):  
REBECA MARCILLA ◽  
DAVID MECERREYES ◽  
IBON ODRIOZOLA ◽  
JOSE A. POMPOSO ◽  
JAVIER RODRIGUEZ ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Gold Nanoparticles ◽  
Ionic Liquid ◽  
Building Block ◽  
Amine Group ◽  
Functional Nanomaterials ◽  
Au Nps ◽  
Functionalized Ionic Liquid ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

In this communication, we report the synthesis of an amino-functionalized ionic liquid (AFIL) and its application as building block in the construction of new functional nanomaterials. This AFIL has been used as surfactant in the synthesis of gold nanoparticles ( Au NPs) and in the development of functional CNTs/IL hybrid nanomaterials by mixing the AFIL with multi-walled carbon nanotubes (MWCNTs). The presence of an amine group in the ionic liquid provides to the resultant nanomaterial with new opportunities in several applications in the nanobio field.

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