High-capacity Si–graphite composite electrodes with a self-formed porous structure by a partially neutralized polyacrylate for Li-ion batteries

2012 ◽  
Vol 5 (10) ◽  
pp. 9014 ◽  
Author(s):  
Zhen-Ji Han ◽  
Naoaki Yabuuchi ◽  
Keiji Shimomura ◽  
Masahiro Murase ◽  
Hiroharu Yui ◽  
...  
2018 ◽  
Vol 165 (5) ◽  
pp. A1110-A1121 ◽  
Author(s):  
Xiuyun Zhao ◽  
Chae-Ho Yim ◽  
Naiying Du ◽  
Yaser Abu-Lebdeh

Materials ◽  
2021 ◽  
Vol 14 (18) ◽  
pp. 5397
Author(s):  
Hyungeun Seo ◽  
Hae-Ri Yang ◽  
Youngmo Yang ◽  
Kyungbae Kim ◽  
Sung Hyon Kim ◽  
...  

Si-based anodes for Li-ion batteries (LIBs) are considered to be an attractive alternative to graphite due to their higher capacity, but they have low electrical conductivity and degrade mechanically during cycling. In the current study, we report on a mass-producible porous Si-CoSi2-C composite as a high-capacity anode material for LIBs. The composite was synthesized with two-step milling followed by a simple chemical etching process. The material conversion and porous structure were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, and electron microscopy. The electrochemical test results demonstrated that the Si-CoSi2-C composite electrode exhibits greatly improved cycle and rate performance compared with conventional Si-C composite electrodes. These results can be ascribed to the role of CoSi2 and inside pores. The CoSi2 synthesized in situ during high-energy mechanical milling can be well attached to the Si; its conductive phase can increase electrical connection with the carbon matrix and the Cu current collectors; and it can accommodate Si volume changes during cycling. The proposed synthesis strategy can provide a facile and cost-effective method to produce Si-based materials for commercial LIB anodes.


2021 ◽  
pp. 2004998
Author(s):  
Huarong Xia ◽  
Yuxin Tang ◽  
Oleksandr I. Malyi ◽  
Zhiqiang Zhu ◽  
Yanyan Zhang ◽  
...  

2020 ◽  
Vol 364 ◽  
pp. 137293
Author(s):  
Jinfang Lin ◽  
Shuyi Chen ◽  
Licai Zhu ◽  
Zhongzhi Yuan ◽  
Jincheng Liu

2013 ◽  
Vol 25 (27) ◽  
pp. 3722-3726 ◽  
Author(s):  
Feng Wu ◽  
Ning Li ◽  
Yuefeng Su ◽  
Haofang Shou ◽  
Liying Bao ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (29) ◽  
pp. 24320-24330 ◽  
Author(s):  
Junkai He ◽  
Ying Liu ◽  
Yongtao Meng ◽  
Xiangcheng Sun ◽  
Sourav Biswas ◽  
...  

A new one-step microwave method was designed for synthesis of rGO/Co3O4, and the Li-ion battery showed high capacity and long life.


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