Zeolitic imidazolate framework (ZIF-8) based polymer nanocomposite membranes for gas separation

2012 ◽  
Vol 5 (8) ◽  
pp. 8359 ◽  
Author(s):  
Qilei Song ◽  
S. K. Nataraj ◽  
Mina V. Roussenova ◽  
Jin Chong Tan ◽  
David J. Hughes ◽  
...  
Keyword(s):  
Gas Separation ◽  
Polymer Nanocomposite ◽  
Nanocomposite Membranes ◽  
Zeolitic Imidazolate Framework

scholarly journals A Review on Polymer Nanocomposites and Their Effective Applications in Membranes and Adsorbents for Water Treatment and Gas Separation

Membranes ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 139
Author(s):  
Oluranti Agboola ◽  
Ojo Sunday Isaac Fayomi ◽  
Ayoola Ayodeji ◽  
Augustine Omoniyi Ayeni ◽  
Edith E. Alagbe ◽  
...  
Keyword(s):  
Greenhouse Gases ◽  
Polymer Nanocomposites ◽  
Gas Separation ◽  
Rapid Growth ◽  
Dye Removal ◽  
Anthropogenic Activities ◽  
Polymer Nanocomposite ◽  
Population Increase ◽  
Nanocomposite Membranes

Globally, environmental challenges have been recognised as a matter of concern. Among these challenges are the reduced availability and quality of drinking water, and greenhouse gases that give rise to change in climate by entrapping heat, which result in respirational illness from smog and air pollution. Globally, the rate of demand for the use of freshwater has outgrown the rate of population increase; as the rapid growth in town and cities place a huge pressure on neighbouring water resources. Besides, the rapid growth in anthropogenic activities, such as the generation of energy and its conveyance, release carbon dioxide and other greenhouse gases, warming the planet. Polymer nanocomposite has played a significant role in finding solutions to current environmental problems. It has found interest due to its high potential for the reduction of gas emission, and elimination of pollutants, heavy metals, dyes, and oil in wastewater. The revolution of integrating developed novel nanomaterials such as nanoparticles, carbon nanotubes, nanofibers and activated carbon, in polymers, have instigated revitalizing and favourable inventive nanotechnologies for the treatment of wastewater and gas separation. This review discusses the effective employment of polymer nanocomposites for environmental utilizations. Polymer nanocomposite membranes for wastewater treatment and gas separation were reviewed together with their mechanisms. The use of polymer nanocomposites as an adsorbent for toxic metals ions removal and an adsorbent for dye removal were also discussed, together with the mechanism of the adsorption process. Patents in the utilization of innovative polymeric nanocomposite membranes for environmental utilizations were discussed.

scholarly journals Fine-scale tribological performance of zeolitic imidazolate framework (ZIF-8) based polymer nanocomposite membranes

APL Materials ◽  
2014 ◽  
Vol 2 (12) ◽  
pp. 124101 ◽  
Author(s):  
Nay Win Khun ◽  
E. M. Mahdi ◽  
Siqi Ying ◽  
Tan Sui ◽  
Alexander M. Korsunsky ◽  
...  
Keyword(s):  
Polymer Nanocomposite ◽  
Tribological Performance ◽  
Fine Scale ◽  
Nanocomposite Membranes ◽  
Zeolitic Imidazolate Framework

Effect of new metal–organic framework (zeolitic imidazolate framework [ZIF-12]) in mixed matrix membranes on structure, morphology, and gas separation properties

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Mehtap Safak Boroglu ◽  
Ismail Boz ◽  
Busra Kaya
Keyword(s):  
Gas Separation ◽  
Gas Permeability ◽  
Metal Organic Framework ◽  
Thermomechanical Analysis ◽  
Variable Pressure ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix ◽  
Sem Images ◽  
Zeolitic Imidazolate Framework ◽  
Matrix Membranes

Abstract In our study, the synthesis of zeolitic imidazolate framework (ZIF-12) crystals and the preparation of mixed matrix membranes (MMMs) with various ZIF-12 loadings were targeted. The characterization of ZIF-12 and MMMs were carried out by Fourier transform infrared spectroscopy analysis, thermogravimetric analysis, scanning electron microscopy (SEM), and thermomechanical analysis. The performance of MMMs was measured by the ability of binary gas separation. Commercial polyetherimide (PEI-Ultem® 1000) polymer was used as the polymer matrix. The solution casting method was utilized to obtain dense MMMs. In the SEM images of ZIF-12 particles, the particles with a rhombic dodecahedron structure were identified. From SEM images, it was observed that the distribution of ZIF-12 particles in the MMMs was homogeneous and no agglomeration was present. Gas permeability experiments of MMMs were measured for H2, CO2, and CH4 gases at steady state, at 4 bar and 35 °C by constant volume-variable pressure method. PEI/ZIF-12-30 wt% MMM exhibited high permeability and ideal selectivity values for H2/CH4 and CO2/CH4 were P H 2 / CH 4 = 331.41 ${P}_{{\text{H}}_{2}/{\text{CH}}_{4}}=331.41$ and P CO 2 / CH 4 = 53.75 ${P}_{{\text{CO}}_{2}/{\text{CH}}_{4}}=53.75$ gas pair.

scholarly journals Ultrathin porous amine-based solid adsorbent incorporated zeolitic imidazolate framework-8 membrane for gas separation

RSC Advances ◽  
2021 ◽  
Vol 11 (46) ◽  
pp. 28863-28875
Author(s):  
Yu Qin ◽  
Li Xu ◽  
Liying Liu ◽  
Xiaoyu Deng ◽  
Yucheng Gao ◽  
...  
Keyword(s):  
Gas Separation ◽  
Zeolitic Imidazolate Framework ◽  
Solid Adsorbent

The amine-based solid adsorbent was innovatively incorporated during the fabrication of the ZIF-8 membrane for gas separation.

Aligned CNT/Polymer nanocomposite membranes for hydrogen separation

2009 ◽  
Vol 34 (9) ◽  
pp. 3977-3982 ◽  
Author(s):  
Anshu Sharma ◽  
Sumit Kumar ◽  
Balram Tripathi ◽  
M. Singh ◽  
Y.K. Vijay
Keyword(s):  
Polymer Nanocomposite ◽  
Hydrogen Separation ◽  
Nanocomposite Membranes

Pyrolysis kinetic behavior and TG-FTIR-GC–MS analysis of end-life ultrafiltration polymer nanocomposite membranes

2021 ◽  
pp. 131181
Author(s):  
Samy Yousef ◽  
Justas Eimontas ◽  
Nerijus Striūgas ◽  
Alaa Mohamed ◽  
Mohammed AliAbdelnaby
Keyword(s):  
Polymer Nanocomposite ◽  
Kinetic Behavior ◽  
Nanocomposite Membranes ◽  
Ms Analysis ◽  
Pyrolysis Kinetic

scholarly journals Polymer Nanocomposite Membranes

2018 ◽  
Vol 8 (7) ◽  
pp. 1181 ◽  
Author(s):  
Svetlana Kononova ◽  
Galina Gubanova ◽  
Eleonora Korytkova ◽  
Denis Sapegin ◽  
Katerina Setnickova ◽  
...  
Keyword(s):  
Thermal Properties ◽  
Polymer Matrix ◽  
Scientific Literature ◽  
Morphological Characteristics ◽  
Polymer Nanocomposite ◽  
Nanocomposite Materials ◽  
Sorption Mechanism ◽  
Nanocomposite Membranes ◽  
Nanocomposite Structure ◽  
Transport Channels

Based on the results of research works reflected in the scientific literature, the main examples, methods and approaches to the development of polymer inorganic nanocomposite materials for target membranes are considered. The focus is on membranes for critical technologies with improved mechanical, thermal properties that have the necessary capabilities to solve the problems of a selective pervaporation. For the purpose of directional changes in the parameters of membranes, effects on their properties of the type, amount and conditions of nanoparticle incorporation into the polymer matrix were analyzed. An influence of nanoparticles on the structural and morphological characteristics of the nanocomposite film is considered, as well as possibilities of forming transport channels for separated liquids are analyzed. Particular attention is paid to a correlation of nanocomposite structure-transport properties of membranes, whose separation characteristics are usually considered within the framework of the diffusion-sorption mechanism.

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