Chemistry of transition metal carbene complexes: nucleophilic substitution reactions of cyanamide anion to Fischer carbene complexes

2013 ◽  
Vol 42 (2) ◽  
pp. 567-576 ◽  
Author(s):  
Sumana Gangopadhyay ◽  
Tarun Mistri ◽  
Malay Dolai ◽  
Rabiul Alam ◽  
Mahammad Ali
Keyword(s):  
Transition Metal ◽  
Nucleophilic Substitution ◽  
Substitution Reactions ◽  
Fischer Carbene Complexes ◽  
Carbene Complexes ◽  
Fischer Carbene ◽  
Nucleophilic Substitution Reactions

scholarly journals Water promoted allylic nucleophilic substitution reactions of (E)-1,3 diphenylallyl acetate

2018 ◽  
Vol 20 (2) ◽  
pp. 425-430 ◽  
Author(s):  
Seema A. Ghorpade ◽  
Dinesh N. Sawant ◽  
Arwa Makki ◽  
Nagaiyan Sekar ◽  
Jörg Eppinger
Keyword(s):  
Transition Metal ◽  
Nucleophilic Substitution ◽  
Allylic Alkylation ◽  
Substitution Reactions ◽  
Allylic Amination ◽  
Metal Free ◽  
Nucleophilic Substitution Reactions ◽  
Water Based

A transition metal free, reagent free, only water based, greener protocol for the allylic alkylation, allylic amination, and O-allylation of (E)-1,3-diphenylallyl acetate is described.

scholarly journals Reversible Carbene Insertion into a Ge−N Bond and Insights into CO and Carbene Substitution Reactions Involving Amidinatogermylenes and Fischer Carbene Complexes

2018 ◽  
Vol 25 (6) ◽  
pp. 1588-1594 ◽  
Author(s):  
Lucía Álvarez-Rodríguez ◽  
Javier A. Cabeza ◽  
Pablo García-Álvarez ◽  
Mar Gómez-Gallego ◽  
Laura González-Álvarez ◽  
...  
Keyword(s):  
Substitution Reactions ◽  
Fischer Carbene Complexes ◽  
Carbene Complexes ◽  
Fischer Carbene ◽  
Carbene Insertion
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