Crystal structure and chemical bonding of the intermetallic Zintl phase Yb11AlSb9

2012 ◽  
Vol 41 (34) ◽  
pp. 10347 ◽  
Author(s):  
Sofie Kastbjerg ◽  
Catherine A. Uvarov ◽  
Susan M. Kauzlarich ◽  
Yu-Sheng Chen ◽  
Eiji Nishibori ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Chemical Bonding ◽  
Zintl Phase

Synthesis, Crystal Structure and Chemical Bonding of the Zintl Phase Rb7NaSi8

2011 ◽  
Vol 637 (13) ◽  
pp. 1982-1991 ◽  
Author(s):  
Thorsten Goebel ◽  
Yurii Prots ◽  
Alim Ormeci ◽  
Oliver Pecher ◽  
Frank Haarmann
Keyword(s):  
Crystal Structure ◽  
Chemical Bonding ◽  
Zintl Phase

The Metallic Zintl Phase Ba3Si4- Synthesis, Crystal Structure, Chemical Bonding, and Physical Properties

2008 ◽  
Vol 634 (10) ◽  
pp. 1651-1661 ◽  
Author(s):  
Umut Aydemir ◽  
Alim Ormeci ◽  
Horst Borrmann ◽  
Bodo Böhme ◽  
Fabio Zürcher ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Physical Properties ◽  
Chemical Bonding ◽  
Zintl Phase

ChemInform Abstract: Zintl-Phase Sr3LiAs2H: Crystal Structure and Chemical Bonding Analysis by the Electron Localizability Approach.

ChemInform ◽  
2015 ◽  
Vol 46 (51) ◽  
pp. no-no
Author(s):  
Xian-Juan Feng ◽  
Yurii Prots ◽  
Matej Bobnar ◽  
Marcus Peter Schmidt ◽  
Walter Schnelle ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Chemical Bonding ◽  
Zintl Phase ◽  
Bonding Analysis

ChemInform Abstract: Synthesis, Crystal Structure and Chemical Bonding of the Zintl Phase Rb7NaSi8.

ChemInform ◽  
2012 ◽  
Vol 43 (7) ◽  
pp. no-no
Author(s):  
Thorsten Goebel ◽  
Yurii Prots ◽  
Alim Ormeci ◽  
Oliver Pecher ◽  
Frank Haarmann
Keyword(s):  
Crystal Structure ◽  
Chemical Bonding ◽  
Zintl Phase

Zintl-Phase Sr3LiAs2H: Crystal Structure and Chemical Bonding Analysis by the Electron Localizability Approach

2015 ◽  
Vol 21 (41) ◽  
pp. 14471-14477 ◽  
Author(s):  
Xian-Juan Feng ◽  
Yurii Prots ◽  
Matej Bobnar ◽  
Marcus Peter Schmidt ◽  
Walter Schnelle ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Chemical Bonding ◽  
Zintl Phase ◽  
Bonding Analysis

ChemInform Abstract: The Cluster Polymers∞1[PtBi6Cl10] and∞1[PtBi6Br10]: Synthesis, Thermochemistry, Crystal Structure and Chemical Bonding.

ChemInform ◽  
2008 ◽  
Vol 39 (11) ◽  
Author(s):  
Folker Steden ◽  
Peer Schmidt ◽  
Bernhard Wahl ◽  
Anna Isaeva ◽  
Michael Ruck
Keyword(s):  
Crystal Structure ◽  
Chemical Bonding

Crystal structure characterization and electronic structure of a rare-earth-containing Zintl phase in the Yb–Al–Sb family: Yb3AlSb3

2021 ◽  
Vol 77 (6) ◽  
Author(s):  
Rongqing Shang ◽  
An T. Nguyen ◽  
Allan He ◽  
Susan M. Kauzlarich
Keyword(s):  
Crystal Structure ◽  
Electronic Structure ◽  
Rare Earth ◽  
Electronic Structure Calculations ◽  
Structure Characterization ◽  
Charge Balance ◽  
X Ray Diffraction ◽  
Zintl Phase ◽  
X Ray ◽  
Structure Calculations

A rare-earth-containing compound, ytterbium aluminium antimonide, Yb3AlSb3 (Ca3AlAs3-type structure), has been successfully synthesized within the Yb–Al–Sb system through flux methods. According to the Zintl formalism, this structure is nominally made up of (Yb2+)3[(Al1−)(1b – Sb2−)2(2b – Sb1−)], where 1b and 2b indicate 1-bonded and 2-bonded, respectively, and Al is treated as part of the covalent anionic network. The crystal structure features infinite corner-sharing AlSb4 tetrahedra, [AlSb2Sb2/2]6−, with Yb2+ cations residing between the tetrahedra to provide charge balance. Herein, the synthetic conditions, the crystal structure determined from single-crystal X-ray diffraction data, and electronic structure calculations are reported.

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