Interfacial kinetics of a model epoxy–amine addition reaction

2012 ◽  
Vol 14 (39) ◽  
pp. 13532 ◽  
Author(s):  
Tomoyasu Hirai ◽  
Kaoru Kawasaki ◽  
Keiji Tanaka
2013 ◽  
Vol 105 (1) ◽  
pp. 146-153 ◽  
Author(s):  
Sheereen Majd ◽  
Erik C. Yusko ◽  
Jerry Yang ◽  
David Sept ◽  
Michael Mayer

2019 ◽  
Vol 2019 ◽  
pp. 1-8
Author(s):  
Masanori Hirose ◽  
Shigenori Sugisaki ◽  
Keishi Suga ◽  
Hiroshi Umakoshi

A method to detect the L-proline- (L-Pro-) catalyzed Michael addition reaction in model biomembranes has been established, using N-[p(2-benzimidazolyl)phenyl]maleimide and acetone as reactants. The effect of liposome membranes on this reaction was kinetically analyzed using fluorescence spectroscopy. The kinetics of the reaction were different from those of the constituent lipids of the liposomes. Zwitterionic 1,2-dipalmitoyl-sn-glycero-3-phosphocholine liposome, which is in the solid-ordered phase, had a better value of reaction rate, suggesting that the reaction rate constants of this reaction in liposome membrane systems could be regulated by the characteristics of the liposome membrane (i.e., the phase state and surface charge). Based on the results obtained, a plausible model of the L-Pro-catalyzed Michael addition reaction was discussed. The obtained results provide us with an easily detectable method to assess the reactivity of L-Pro in biological systems.


2020 ◽  
Vol 692 ◽  
pp. 178735
Author(s):  
Zhipeng Ran ◽  
Xiaobing Liu ◽  
Xiaolian Jiang ◽  
Yeping Wu ◽  
Hong Liao

1990 ◽  
Vol 22 (12) ◽  
pp. 1035-1042 ◽  
Author(s):  
Eiichi Kobayashi ◽  
Takatsugu Obata ◽  
Sadahito Aoshima ◽  
Junji Furukawa

1983 ◽  
Vol 14 (3) ◽  
pp. 504-506
Author(s):  
C. H. Hua ◽  
N. A. D. Parlee

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