Remarkable dependence of electrochemical performance of SrCo0.8Fe0.2O3-δ on A-site nonstoichiometry

2012 ◽  
Vol 14 (20) ◽  
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Huanying Liu ◽  
Xuefeng Zhu ◽  
You Cong ◽  
Tianyu Zhang ◽  
Weishen Yang
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Weihua Ma ◽  
Qin Zhong ◽  
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RSC Advances ◽  
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Ye Lin ◽  
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Sr0.95Nb0.1Co0.9O3−δ (P4/mmm crystal structure), displaying a large JT distortion combined with charge-ordering of cobalt, shows improved ORR activity at low temperature, whereas Sr0.98Nb0.1Co0.9O3−δ (P4mm crystal structure), with a slight JT distortion, shows diminished performance.


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