Realisation of an all solid state lithium battery using solid high temperature plastic crystal electrolytes exhibiting liquid like conductivity

2012 ◽  
Vol 14 (13) ◽  
pp. 4597 ◽  
Author(s):  
Youssof Shekibi ◽  
Thomas Rüther ◽  
Junhua Huang ◽  
Anthony F. Hollenkamp
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Lithium Battery ◽  
Plastic Crystal

High-Temperature Solid-State Dye-Sensitized Solar Cells Based on Organic Ionic Plastic Crystal Electrolytes

2012 ◽  
Vol 24 (7) ◽  
pp. 945-950 ◽  
Author(s):  
Qing Li ◽  
Jie Zhao ◽  
Baoquan Sun ◽  
Bencai Lin ◽  
Lihua Qiu ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Temperature ◽  
Solid State ◽  
Dye Sensitized Solar Cells ◽  
Plastic Crystal ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

High temperature property of all-solid-state thin film lithium battery using LiPON electrolyte

2014 ◽  
Vol 134 ◽  
pp. 237-239 ◽  
Author(s):  
Dezhan Li ◽  
Zhongyun Ma ◽  
Jing Xu ◽  
Yujie Li ◽  
Kai Xie
Keyword(s):  
Thin Film ◽  
High Temperature ◽  
Solid State ◽  
Lithium Battery ◽  
Temperature Property ◽  
High Temperature Property

Solid-state reaction of niobium with diamond carbon at high pressure and high temperature to form superconducting composite

2021 ◽  
Vol 31 (3) ◽  
pp. 415-418
Author(s):  
Vladimir Yu. Osipov ◽  
Fedor M. Shakhov ◽  
Nikolai M. Romanov ◽  
Kazuyuki Takai
Keyword(s):  
High Pressure ◽  
High Temperature ◽  
Solid State ◽  
Solid State Reaction

A safeguarding and high temperature tolerant organogel electrolyte for flexible solid-state supercapacitors

2021 ◽  
Vol 505 ◽  
pp. 230083
Author(s):  
Yuxuan Wu ◽  
Sheng Wang ◽  
Min Sang ◽  
Quan Shu ◽  
Junshuo Zhang ◽  
...  
Keyword(s):  
High Temperature ◽  
Solid State

scholarly journals HKUST-1@IL-Li Solid-state Electrolyte with 3D Ionic Channels and Enhanced Fast Li+ Transport for Lithium Metal Batteries at High Temperature

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 736
Author(s):  
Man Li ◽  
Tao Chen ◽  
Seunghyun Song ◽  
Yang Li ◽  
Joonho Bae
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Solid Electrolyte ◽  
Metal Organic Framework ◽  
Ionic Channels ◽  
Transference Numbers ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Metal Organic ◽  
Organic Framework

The challenge of safety problems in lithium batteries caused by conventional electrolytes at high temperatures is addressed in this study. A novel solid electrolyte (HKUST-1@IL-Li) was fabricated by immobilizing ionic liquid ([EMIM][TFSI]) in the nanopores of a HKUST-1 metal–organic framework. 3D angstrom-level ionic channels of the metal–organic framework (MOF) host were used to restrict electrolyte anions and acted as “highways” for fast Li+ transport. In addition, lower interfacial resistance between HKUST-1@IL-Li and electrodes was achieved by a wetted contact through open tunnels at the atomic scale. Excellent high thermal stability up to 300 °C and electrochemical properties are observed, including ionic conductivities and Li+ transference numbers of 0.68 × 10-4 S·cm-1 and 0.46, respectively, at 25 °C, and 6.85 × 10-4 S·cm-1 and 0.68, respectively, at 100 °C. A stable Li metal plating/stripping process was observed at 100 °C, suggesting an effectively suppressed growth of Li dendrites. The as-fabricated LiFePO4/HKUST-1@IL-Li/Li solid-state battery exhibits remarkable performance at high temperature with an initial discharge capacity of 144 mAh g-1 at 0.5 C and a high capacity retention of 92% after 100 cycles. Thus, the solid electrolyte in this study demonstrates promising applicability in lithium metal batteries with high performance under extreme thermal environmental conditions.

scholarly journals Modeling and Simulation in Capacity Degradation and Control of All-Solid-State Lithium Battery Based on Time-Aging Polymer Electrolyte

Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1206
Author(s):  
Xuansen Fang ◽  
Yaolong He ◽  
Xiaomin Fan ◽  
Dan Zhang ◽  
Hongjiu Hu
Keyword(s):  
Solid State ◽  
Lithium Battery ◽  
Lithium Salt ◽  
Operating Temperature ◽  
Discharge Rate ◽  
Salt Content ◽  
Lithium Ion ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Capacity Degradation

The prediction of electrochemical performance is the basis for long-term service of all-solid-state-battery (ASSB) regarding the time-aging of solid polymer electrolytes. To get insight into the influence mechanism of electrolyte aging on cell fading, we have established a continuum model for quantitatively analyzing the capacity evolution of the lithium battery during the time-aging process. The simulations have unveiled the phenomenon of electrolyte-aging-induced capacity degradation. The effects of discharge rate, operating temperature, and lithium-salt concentration in the electrolyte, as well as the electrolyte thickness, have also been explored in detail. The results have shown that capacity loss of ASSB is controlled by the decrease in the contact area of the electrolyte/electrode interface at the initial aging stage and is subsequently dominated by the mobilities of lithium-ion across the aging electrolyte. Moreover, reducing the discharge rate or increasing the operating temperature can weaken this cell deterioration. Besides, the thinner electrolyte film with acceptable lithium salt content benefits the durability of the ASSB. It has also been found that the negative effect of the aging electrolytes can be relieved if the electrolyte conductivity is kept being above a critical value under the storage and using conditions.

Photoluminescence Properties of Ca3Si2O7: Pr3+ Orange-Red Phosphors Prepared by High-Temperature Solid-State Method

2018 ◽  
Vol 73 (6) ◽  
pp. 555-558 ◽  
Author(s):  
Zhi-Qing Peng ◽  
Rong Chen ◽  
Wen-Lin Feng
Keyword(s):  
Crystal Structure ◽  
High Temperature ◽  
Solid State ◽  
Solid State Method ◽  
Light Emitting ◽  
Light Emitting Devices ◽  
Red Phosphors ◽  
Typical Sample ◽  
State Method ◽  
Xrd Patterns

AbstractNovel luminescent materials Ca3-xSi2O7: xPr3+ were successfully prepared by the high-temperature solid-state method. The crystal structure, morphology, and optical spectrum were characterised by X-ray diffraction (XRD), scanning electron microscopy (SEM), and spectroscopy, respectively. The XRD patterns of the samples indicate that the crystal structure is monoclinic symmetry. The SEM shows that the selected sample has good crystallinity although its appearance is irregular and scalelike. The peak of the excitation spectrum of the sample is located at around 449 nm, corresponding to 3H4→3P2 transition of Pr3+. The peak of the emission spectrum of the sample is situated at around 612 nm which is attributed to 3P0→3H6 transition of Pr3+, and the colour is orange-red. The optimum concentration for Pr3+ replaced Ca2+ sites in Ca3Si2O7: Pr3+ is 0.75 mol%. The lifetime (8.48 μs) of a typical sample (Ca2.9925Pr0.0075)Si2O7 is obtained. It reveals that orange-red phosphors Ca3-xSi2O7: xPr3+ possess remarkable optical properties and can be used in white light emitting devices.

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