Synthesis and characterization of cobalt(iii) cyanide complexes: cobalt participation in the decomposition of radical anion of TCNQ

CrystEngComm ◽  
2012 ◽  
Vol 14 (24) ◽  
pp. 8708 ◽  
Author(s):  
Chun-Hong Tan ◽  
Xiao Ma ◽  
Qi-Long Zhu ◽  
Yi-Hui Huang ◽  
Yue-Hong Wen ◽  
...  
Keyword(s):  
Radical Anion ◽  
Synthesis And Characterization ◽  
Cyanide Complexes

Synthesis and characterization of 2,7-bis(2-pyridyl)-1,8-diazaanthraquinone — A redox-active ligand designed for the construction of supramolecular grids

2006 ◽  
Vol 84 (10) ◽  
pp. 1263-1267 ◽  
Author(s):  
Rajsapan Jain ◽  
Sharon L Caldwell ◽  
Anika S Louie ◽  
Robin G Hicks
Keyword(s):  
Radical Anion ◽  
Synthesis And Characterization ◽  
Electrochemical Studies ◽  
Reduction Processes ◽  
Redox Active Ligand ◽  
Active Ligand ◽  
Redox Active ◽  
Metallosupramolecular Chemistry ◽  
Reversible Reduction

Double condensation of 2-acetylpyridine with 1,3-diaminobenzene-4,6-dicarboxaldehyde affords 2,7-bis(2-pyridyl)-1,8-diazaanthracene, which was subsequently oxidized to the corresponding quinone. Electrochemical studies indicate two reversible reduction processes corresponding to semiquinone and hydroquinonate formation. Electron-withdrawing pyridine groups and the nitrogen atoms make this somewhat more easily reduced than anthraquinone. This compound is redox-active and can be reduced to its radical anion, a potential spin-bearing ligand for the construction of [2 × 2] metallo-grid structures.Key words: quinone, grid, supramolecular, bistridentate, electrochemistry, metallosupramolecular chemistry.

Nucleophilic properties and electrochemistry of five-coordinate rhodium(I) .sigma.-cyanide complexes. Synthesis and characterization of stable cis hydride cyanide complexes of rhodium(III)

1989 ◽  
Vol 8 (4) ◽  
pp. 893-899 ◽  
Author(s):  
Claudio. Bianchini ◽  
Franco. Laschi ◽  
M. Francesca. Ottaviani ◽  
Maurizio. Peruzzini ◽  
Piero. Zanello ◽  
...  
Keyword(s):  
Synthesis And Characterization ◽  
Cyanide Complexes

Technetium cyanide chemistry: synthesis and characterization of technetium(III) and -(V) cyanide complexes

1980 ◽  
Vol 19 (7) ◽  
pp. 1993-1997 ◽  
Author(s):  
Harvey S. Trop ◽  
Alun G. Jones ◽  
Alan Davison
Keyword(s):  
Synthesis And Characterization ◽  
Cyanide Complexes

Synthesis and characterization of two copper cyanide complexes with hexagonal Cu6 units

2000 ◽  
pp. 1685-1686 ◽  
Author(s):  
Yingjun Zhao ◽  
Maochun Hong ◽  
Weiping Su ◽  
Rong Cao ◽  
Zhongyuan Zhou ◽  
...  
Keyword(s):  
Synthesis And Characterization ◽  
Copper Cyanide ◽  
Cyanide Complexes

Synthesis and Characterization of the Three Dicyclopentapyrenes

1996 ◽  
Vol 61 (10) ◽  
pp. 3572-3572
Author(s):  
Lawrence T. Scott ◽  
Atena Necula
Keyword(s):  
Synthesis And Characterization
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