Porous metal–organic framework based on a macrocyclic tetracarboxylate ligand exhibiting selective CO2 uptake

CrystEngComm ◽  
2012 ◽  
Vol 14 (19) ◽  
pp. 6115 ◽  
Author(s):  
Wen-Yang Gao ◽  
Youhong Niu ◽  
Yao Chen ◽  
Lukasz Wojtas ◽  
Jianfeng Cai ◽  
...  
CrystEngComm ◽  
2014 ◽  
Vol 16 (28) ◽  
pp. 6287-6290 ◽  
Author(s):  
Mingxing Zhang ◽  
Qian Wang ◽  
Zhiyong Lu ◽  
Huiyan Liu ◽  
Wenlong Liu ◽  
...  

A nitro-decorated and highly porous metal–organic framework with NbO topology was reported, exhibiting good adsorption selectivity of CO2/CH4 (8) and CO2/N2 (24) at 273 K and 1 bar, high methane total uptake of 184 cm3 cm−3 at 290 K and 35 bar.


CrystEngComm ◽  
2020 ◽  
Vol 22 (19) ◽  
pp. 3378-3384 ◽  
Author(s):  
Cheng He ◽  
Chao Hou ◽  
Yu Min Wang ◽  
Xue Yong Gong ◽  
Hong Li Jiang ◽  
...  

A robust porous metal–organic framework with dual functionalities of open metal sites (OMSs) and O-rich Lewis basic sites (LBSs) has been designed and synthesized, and shows high CO2 uptake and excellent selectivity for CO2 over N2 and CH4.


2018 ◽  
Vol 57 (12) ◽  
pp. 7244-7251 ◽  
Author(s):  
Ioannis Bratsos ◽  
Christos Tampaxis ◽  
Ioannis Spanopoulos ◽  
Nicola Demitri ◽  
Georgia Charalambopoulou ◽  
...  

Author(s):  
Arpan Hazra ◽  
Satyanarayana Bonakala ◽  
Stephen Adie Adalikwu ◽  
Sundaram Balasubramanian ◽  
Tapas Kumar Maji

2021 ◽  
Vol 23 (3) ◽  
pp. 1220-1227
Author(s):  
Aisha Asghar ◽  
Naseem Iqbal ◽  
Tayyaba Noor ◽  
Benson M. Kariuki ◽  
Luke Kidwell ◽  
...  

Electrochemical synthesis, from manganese strips and dissolved linker, of a new amine-containing manganese-based metal–organic framework with enhanced CO2 uptake.


2021 ◽  
Vol 143 (3) ◽  
pp. 1365-1376
Author(s):  
Sérgio M. F. Vilela ◽  
Jorge A. R. Navarro ◽  
Paula Barbosa ◽  
Ricardo F. Mendes ◽  
Germán Pérez-Sánchez ◽  
...  

2014 ◽  
Vol 50 (14) ◽  
pp. 1678-1681 ◽  
Author(s):  
Jinjie Qian ◽  
Feilong Jiang ◽  
Linjie Zhang ◽  
Kongzhao Su ◽  
Jie Pan ◽  
...  

A highly porous metal–organic framework structurally consists of three topological kinds of 3-connected 1,3,5-benzenetricarboxylate ligands, Zn2(COO)4, Zn3O(COO)6 and Zn4O(COO)6 SBUs, featuring a new 3,3,3,4,4,6-c hexanodal topology.


2010 ◽  
Vol 49 (21) ◽  
pp. 9852-9862 ◽  
Author(s):  
Christophe Volkringer ◽  
Thierry Loiseau ◽  
Nathalie Guillou ◽  
Gérard Férey ◽  
Mohamed Haouas ◽  
...  

2021 ◽  
Vol 896 ◽  
pp. 13-20
Author(s):  
Xiao Yu Wen

As an important factor to measure environmental comfort, humidity control is very important. However, previous dehumidification methods have many defects, such as condensation and adsorbents, which often require a lot of energy. The growing requirements of an indoor environment can stem from the development of living levels and technology. Humidity, as an important factor to measure environmental comfort, affects living and production, and indoor humidity control is an indispensable part of modern architecture. However, there are many defects in the previous dehumidification methods, such as condensation dehumidification, which often requires a lot of energy. Traditional adsorbents (such as zeolite silica and activated alumina) have problems with fragile structures or high regeneration temperatures. In this paper, an indoor dehumidification device based on the porous metal-organic framework {MOF-801, Zr6O4(OH)4(Fumarate)6}, can realize the indoor dehumidification process only by using a small amount of solar energy (1 kilowatt per square meter). The device is expected to remove 0.2113 kg/h of moisture per square meter MOF-801, only needs a few additional energy inputs.


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