Solvent influences structural variation from a 3D 4-fold interpenetrated framework to a 2D layer-type porous coordination polymer: Structure analysis and highly selective gas adsorption properties

CrystEngComm ◽  
2012 ◽  
Vol 14 (8) ◽  
pp. 2954 ◽  
Author(s):  
Bo Liu ◽  
Hui Miao ◽  
Ling-Yan Pang ◽  
Lei Hou ◽  
Yao-Yu Wang ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Structure Analysis ◽  
Structural Variation ◽  
Gas Adsorption ◽  
Polymer Structure ◽  
Adsorption Properties ◽  
Porous Coordination Polymer

scholarly journals Soft 2D Layer Porous Coordination Polymers with 1,2-Di(4-pyridyl)ethane

2013 ◽  
Vol 66 (4) ◽  
pp. 464 ◽  
Author(s):  
Keisuke Kishida ◽  
Satoshi Horike ◽  
Kanokwan Kongpatpanich ◽  
Susumu Kitagawa
Keyword(s):  
Coordination Polymer ◽  
Crystal Structures ◽  
Coordination Polymers ◽  
Adsorption Isotherms ◽  
Gas Adsorption ◽  
Porous Structures ◽  
Porous Coordination Polymers ◽  
Substituent Group ◽  
Layer Structures ◽  
Porous Coordination Polymer

Porous coordination polymer compounds consisting of Zn2+, 1,2-di(4-pyridyl)ethane, and dicarboxylates were synthesised and their crystal structures were determined. These are doubly interpenetrated 2D layer structures, and the flexibility of porous structures is dependent on the substituent group of the dicarboxylate. From gas adsorption studies, distinct adsorption isotherms were observed for CO2, CH4, C2H4, and C2H6 at 195 K and 273 K, respectively.

Water adsorption properties of a Sc(iii) porous coordination polymer for CO2 capture applications

2015 ◽  
Vol 2 (12) ◽  
pp. 1080-1084 ◽  
Author(s):  
J. Raziel Álvarez ◽  
Ricardo A. Peralta ◽  
Jorge Balmaseda ◽  
Eduardo González-Zamora ◽  
Ilich A. Ibarra
Keyword(s):  
Relative Humidity ◽  
Coordination Polymer ◽  
Co2 Capture ◽  
Water Adsorption ◽  
Fold Increase ◽  
Adsorption Properties ◽  
Porous Coordination Polymer

Water adsorption was investigated in the hydrostable Sc(iii) coordination polymer NOTT-400. This material performed CO2 capture under relative humidity (RH) conditions (20 and 10% RH). The maximum CO2 capture was obtained at 20% RH and 30 °C with a total amount of ∼10.2 wt%, representing a 2.5-fold increase in comparison with anhydrous conditions.

scholarly journals Borderline microporous–ultramicroporous palladium(ii) coordination polymer networks. Effect of pore functionalisation on gas adsorption properties

2007 ◽  
Vol 17 (19) ◽  
pp. 1939-1946 ◽  
Author(s):  
Jorge A. R. Navarro ◽  
Elisa Barea ◽  
Juan M. Salas ◽  
Norberto Masciocchi ◽  
Simona Galli ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Gas Adsorption ◽  
Polymer Networks ◽  
Adsorption Properties

scholarly journals Cover Picture: A Soft Copper(II) Porous Coordination Polymer with Unprecedented Aqua Bridge and Selective Adsorption Properties (Chem. Eur. J. 41/2012)

2012 ◽  
Vol 18 (41) ◽  
pp. 12905-12905
Author(s):  
Elsa Quartapelle Procopio ◽  
Tomohiro Fukushima ◽  
Elisa Barea ◽  
Jorge A. R. Navarro ◽  
Satoshi Horike ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Selective Adsorption ◽  
Adsorption Properties ◽  
Porous Coordination Polymer

A Soft Copper(II) Porous Coordination Polymer with Unprecedented Aqua Bridge and Selective Adsorption Properties

2012 ◽  
Vol 18 (41) ◽  
pp. 13117-13125 ◽  
Author(s):  
Elsa Quartapelle Procopio ◽  
Tomohiro Fukushima ◽  
Elisa Barea ◽  
Jorge A. R. Navarro ◽  
Satoshi Horike ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Selective Adsorption ◽  
Adsorption Properties ◽  
Porous Coordination Polymer

A titanium-based porous coordination polymer as a catalyst for chemical fixation of CO2

2017 ◽  
Vol 5 (19) ◽  
pp. 9163-9168 ◽  
Author(s):  
Ya Du ◽  
Haishen Yang ◽  
Shun Wan ◽  
Yinghua Jin ◽  
Wei Zhang
Keyword(s):  
Coordination Polymer ◽  
Gas Adsorption ◽  
Catalytic Conversion ◽  
Titanium Alkoxide ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Porous Coordination Polymer

We report the synthesis of a porous coordination polymer consisting of titanium alkoxide linkages and its application in gas adsorption/separation and catalytic conversion of CO2 to cyclic carbonates.

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