Anion-dependent assembly and solvent-mediated structural transformations of three Cd(ii) coordination polymers based on 1H-imidazole-4-carboxylic acid

CrystEngComm ◽  
2012 ◽  
Vol 14 (6) ◽  
pp. 2308 ◽  
Author(s):  
Song-Liang Cai ◽  
Mei Pan ◽  
Sheng-Run Zheng ◽  
Jing-Bo Tan ◽  
Jun Fan ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Coordination Polymers ◽  
Structural Transformations

scholarly journals Photoluminescent Coordination Polymers Based on Group 12 Metals and 1H-Indazole-6-Carboxylic Acid

Inorganics ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 20
Author(s):  
Antonio A. García-Valdivia ◽  
Estitxu Echenique-Errandonea ◽  
Gloria B. Ramírez-Rodríguez ◽  
José M. Delgado-López ◽  
Belén Fernández ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Coordination Polymers ◽  
Density Functional ◽  
Free Ligand ◽  
Emission Spectra ◽  
Point Of View ◽  
Theoretical Point ◽  
Fourier Transformed Infrared Spectroscopy ◽  
3D Network ◽  
The Stability

Two new coordination polymers (CPs) based on Zn(II) and Cd(II) and 1H-indazole-6-carboxylic acid (H2L) of general formulae [Zn(L)(H2O)]n (1) and [Cd2(HL)4]n (2) have been synthesized and fully characterized by elemental analyses, Fourier transformed infrared spectroscopy and single crystal X-ray diffraction. The results indicate that compound 1 possesses double chains in its structure whereas 2 exhibits a 3D network. The intermolecular interactions, including hydrogen bonds, C–H···π and π···π stacking interactions, stabilize both crystal structures. Photoluminescence (PL) properties have shown that compounds 1 and 2 present similar emission spectra compared to the free-ligand. The emission spectra are also studied from the theoretical point of view by means of time-dependent density-functional theory (TD-DFT) calculations to confirm that ligand-centred π-π* electronic transitions govern emission of compound 1 and 2. Finally, the PL properties are also studied in aqueous solution to explore the stability and emission capacity of the compounds.

Carboxylic Acid-Doped SBA-15 Silica as a Host for Metallo-supramolecular Coordination Polymers†

2008 ◽  
Vol 112 (46) ◽  
pp. 14637-14647 ◽  
Author(s):  
D. Akcakayiran ◽  
D. Mauder ◽  
C. Hess ◽  
T. K. Sievers ◽  
D. G. Kurth ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Coordination Polymers ◽  
Supramolecular Coordination

Temperature-induced structural transformations accompanied by changes in magnetic properties of two copper coordination polymers

CrystEngComm ◽  
2020 ◽  
Vol 22 (20) ◽  
pp. 3482-3488 ◽  
Author(s):  
Jing Tu ◽  
Hongjuan Chen ◽  
Hongju Tian ◽  
Xianyong Yu ◽  
Baishu Zheng ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymers ◽  
Structural Transformations ◽  
Organic Ligands ◽  
Coordination Modes ◽  
Copper Compounds ◽  
Copper Coordination

Two ferromagnetic copper compounds have been synthesized under different temperature, which represented the rare example of structural transformations resulting from the coordination modes of organic ligands supported by magnetic results.

Metal carbonyl cluster-based coordination polymers: diverse syntheses, versatile network structures, and special properties

CrystEngComm ◽  
2019 ◽  
Vol 21 (48) ◽  
pp. 7341-7364 ◽  
Author(s):  
Minghuey Shieh ◽  
Yu-Hsin Liu ◽  
Yu-Huei Li ◽  
Ru Yan Lin
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymers ◽  
Recent Progress ◽  
Metal Carbonyl ◽  
Structural Transformations ◽  
Network Structures ◽  
Carbonyl Cluster ◽  
Metal Carbonyl Cluster

This highlight surveys recent progress in groups 6–10 metal carbonyl cluster-based coordination polymers, focusing on diverse synthetic strategies, versatile structures, structural transformations, and semiconducting as well as magnetic properties.

Solid-State Structural Transformations and Photoreactivity of 1D-Ladder Coordination Polymers of PbII

2013 ◽  
Vol 19 (12) ◽  
pp. 3962-3968 ◽  
Author(s):  
Goutam Kumar Kole ◽  
Abdul Malik Puthan Peedikakkal ◽  
Belinda Mei Fang Toh ◽  
Jagadese J. Vittal
Keyword(s):  
Solid State ◽  
Coordination Polymers ◽  
Structural Transformations

Synthesis, structure and photocatalytic properties of coordination polymers based on pyrazole carboxylic acid ligands

CrystEngComm ◽  
2020 ◽  
Vol 22 (41) ◽  
pp. 6847-6855
Author(s):  
Chen-Lan Lin ◽  
Yan-Fei Chen ◽  
Li-Juan Qiu ◽  
Binglong Zhu ◽  
Xin Wang ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Coordination Polymers ◽  
Photocatalytic Properties ◽  
Acid Ligand ◽  
Photocatalytic Activities ◽  
Carboxylic Acid Ligand

The photocatalytic activities of two novel different 2-D coordination polymers constructed from 5-hydroxy-1H-pyrazole-3-carboxylic acid ligand have been explored.

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