Hexagonal prismatic dodecameric water cluster: a building unit of the five-fold interpenetrating six-connected supramolecular network

2012 ◽  
Vol 48 (72) ◽  
pp. 9014 ◽  
Author(s):  
Xiaoju Li ◽  
Xiahong Xu ◽  
Daqiang Yuan ◽  
Xiulan Weng
Keyword(s):  
Water Cluster ◽  
Supramolecular Network ◽  
Building Unit ◽  
Cluster A

scholarly journals Poly[[(methanol)(μ4-2,4,5,6-tetrafluorobenzene-1,3-dicarboxylato)copper(II)] methanol monosolvate]

2012 ◽  
Vol 68 (6) ◽  
pp. m768-m769 ◽  
Author(s):  
Dan Yan ◽  
Qian Duan
Keyword(s):  
Hydrogen Bonds ◽  
Benzene Ring ◽  
Layered Structure ◽  
Title Compound ◽  
Three Dimensional ◽  
Dihedral Angles ◽  
Supramolecular Network ◽  
Secondary Building Unit ◽  
Building Unit ◽  
Carboxylate Groups

In the title compound, {[Cu(C8F4O4)(CH3OH)]·CH3OH} n , two CuII atoms are bridged by four carboxylate groups, forming the well known paddle-wheel secondary building unit (SBU) with axial methanol ligands. In each ligand, the dihedral angles between the benzene ring and the two carboxylate groups are 80.43 (17) and 62.5 (4)°. Within each SBU, the four carboxylate groups come from four symmetry-equivalent tetrafluoroisophthalate ligands. Each tetrafluoroisophthalate group connects two SBUs, forming a layered structure . In the crystal, O—H...O hydrogen bonds involving the free and ligated methanol molecules link the molecules into a three-dimensional supramolecular network.

H-Bonded Porous Supramolecular Network of a CuIIComplex Assisted by Assembled 2D Sheet of Chair Form Hexameric Water Cluster

2008 ◽  
Vol 2008 (26) ◽  
pp. 4166-4172 ◽  
Author(s):  
Kafeel Ahmad Siddiqui ◽  
Gopal K. Mehrotra ◽  
Jerzy Mrozinski ◽  
Raymond J. Butcher
Keyword(s):  
Water Cluster ◽  
Supramolecular Network ◽  
Chair Form

Supramolecular Network of Triaminotriptycene and Its Water Cluster Guest: Synthesis, Structure, and Characterization of [(tatp)4·17H2O]n

2018 ◽  
Vol 18 (3) ◽  
pp. 1629-1635 ◽  
Author(s):  
Li Liu ◽  
Yun Zhang ◽  
Xiao-Li Wang ◽  
Geng-Geng Luo ◽  
Zi-Jing Xiao ◽  
...  
Keyword(s):  
Water Cluster ◽  
Supramolecular Network

scholarly journals Ligand-Rearrangement-Induced Transformation from a 3D Supramolecular Network to a Discrete Octanuclear Cluster: A Good Detector for Pb2+ and Cr2O72–

ACS Omega ◽  
2019 ◽  
Vol 4 (7) ◽  
pp. 11493-11499 ◽  
Author(s):  
Dan-Dan Yang ◽  
Yue Liu ◽  
ShuangShuang Li ◽  
Lin Cheng ◽  
Ying Wang ◽  
...  
Keyword(s):  
Supramolecular Network ◽  
Cluster A

Hydrated anion glued capsular and non-capsular assembly of a tripodal host: Solid state recognition of bromide–water [Br5–(H2O)6]5− and iodide–water [I2–(H2O)4]2− clusters in cationic tripodal receptor

CrystEngComm ◽  
2014 ◽  
Vol 16 (21) ◽  
pp. 4447-4458 ◽  
Author(s):  
Md. Najbul Hoque ◽  
Gopal Das
Keyword(s):  
Solid State ◽  
Water Cluster ◽  
Supramolecular Network ◽  
State Recognition ◽  
Tripodal Receptor ◽  
Hydrated Anion

In this report we describe capsular and non-capsular assembly of polyammonium tripodal receptor into supramolecular network driven by anion or anion–water cluster and solid state recognition of unique bromide–water [Br5–(H2O)6]5− and iodide–water [I2–(H2O)4]2− clusters.

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