Efficient photocatalytic hydrogen evolution over hydrogenated ZnO nanorod arrays

2012 ◽  
Vol 48 (62) ◽  
pp. 7717-7719 ◽  
Author(s):  
Xihong Lu ◽  
Gongming Wang ◽  
Shilei Xie ◽  
Jianying Shi ◽  
Wei Li ◽  
...  

Hydrogenated ZnO nanorod arrays grown on FTO substrates yield a benchmark specific hydrogen production rate of 122 500 μmol h−1 g−1.

2020 ◽  
Vol 56 (71) ◽  
pp. 10378-10378
Author(s):  
Xihong Lu ◽  
Gongming Wang ◽  
Shilei Xie ◽  
Jianying Shi ◽  
Wei Li ◽  
...  

Correction for ‘Efficient photocatalytic hydrogen evolution over hydrogenated ZnO nanorod arrays’ by Xihong Lu et al., Chem. Commun., 2012, 48, 7717–7719, DOI: 10.1039/C2CC31773G.


2017 ◽  
Vol 5 (37) ◽  
pp. 19649-19655 ◽  
Author(s):  
Weiren Cheng ◽  
Hui Su ◽  
Fumin Tang ◽  
Wei Che ◽  
Yuanyuan Huang ◽  
...  

We report a newly designed Au cluster-nanoparticle/C3N4 photocatalyst for realizing efficient plasmonic hot-electron injection, which could effectively improve the hydrogen production rate by 6–20 times in the 400–900 nm range.


2020 ◽  
Vol 10 (15) ◽  
pp. 5298-5305
Author(s):  
Xuanxuan Yang ◽  
Yu Guo ◽  
Yongbing Lou ◽  
Jinxi Chen

The reaction mechanism of O-MoS2/Mn0.5Cd0.5S for photocatalytic hydrogen evolution is put forward and the satisfactory hydrogen production rate of the optimized composite is superior to most of the Mn–Cd–S based catalysts reported.


2014 ◽  
Vol 50 (14) ◽  
pp. 1731-1734 ◽  
Author(s):  
Zheng Wang ◽  
Jungang Hou ◽  
Chao Yang ◽  
Shuqiang Jiao ◽  
Hongmin Zhu

Three-dimensional MoS2–CdS–γ-TaON hollow nanostructures as novel photocatalysts were firstly synthesized via a facile hydrothermal method and they exhibit a high photocatalytic hydrogen production rate without a noble metal.


2020 ◽  
Vol 16 ◽  
Author(s):  
Yuxue Wei ◽  
Honglin Qin ◽  
Jinxin Deng ◽  
Xiaomeng Cheng ◽  
Mengdie Cai ◽  
...  

Introduction: Solar-driven photocatalytic hydrogen production from water splitting is one of the most promising solutions to satisfy the increasing demands of a rapidly developing society. CdS has emerged as a representative semiconductor photocatalyst due to its suitable band gap and band position. However, the poor stability and rapid charge recombination of CdS restrict its application for hydrogen production. The strategy of using a cocatalyst is typically recognized as an effective approach for improving the activity, stability, and selectivity of photocatalysts. In this review, recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation are summarized. In particular, the factors affecting the photocatalytic performance and new cocatalyst design, as well as the general classification of cocatalysts, are discussed, which includes a single cocatalyst containing noble-metal cocatalysts, non-noble metals, metal-complex cocatalysts, metal-free cocatalysts, and multi-cocatalysts. Finally, future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are described. Background: Photocatalytic hydrogen evolution from water splitting using photocatalyst semiconductors is one of the most promising solutions to satisfy the increasing demands of a rapidly developing society. CdS has emerged as a representative semiconductor photocatalyst due to its suitable band gap and band position. However, the poor stability and rapid charge recombination of CdS restrict its application for hydrogen production. The strategy of using a cocatalyst is typically recognized as an effective approach for improving the activity, stability, and selectivity of photocatalysts. Methods: This review summarizes the recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation. Results: Recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation are summarized. The factors affecting the photocatalytic performance and new cocatalyst design, as well as the general classification of cocatalysts, are discussed, which includes a single cocatalyst containing noble-metal cocatalysts, non-noble metals, metal-complex cocatalysts, metal-free cocatalysts, and multi-cocatalysts. Finally, future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are described. Conclusion: The state-of-the-art CdS for producing hydrogen from photocatalytic water splitting under visible light is discussed. The future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are also described.


2012 ◽  
Vol 4 (6) ◽  
pp. 2969-2977 ◽  
Author(s):  
Dian-bo Zhang ◽  
Shu-jie Wang ◽  
Ke Cheng ◽  
Shu-xi Dai ◽  
Bin-bin Hu ◽  
...  

2017 ◽  
Vol 67 ◽  
pp. 55-61 ◽  
Author(s):  
Xiao-Feng Su ◽  
Jian-Biao Chen ◽  
Ru-Mei He ◽  
Yan Li ◽  
Jian Wang ◽  
...  

2012 ◽  
Vol 16 (5) ◽  
pp. 326-331 ◽  
Author(s):  
Q F Sun ◽  
Y Lu ◽  
H M Zhang ◽  
D J Yang ◽  
J S Xu ◽  
...  

2020 ◽  
Vol 20 (6) ◽  
pp. 3512-3518
Author(s):  
Saleh Khan ◽  
Xiao-He Liu ◽  
Xi Jiang ◽  
Qing-Yun Chen

Highly efficient and effective porous ZnO nanorod arrays were fabricated by annealing ZnO nanorod arrays grown on a substrate using a simple hydrothermal method. The annealing had a positive effect on the nanorod morphology, structure and optical properties. The porosity was closely related to the annealing temperature. After heating at 450 °C, pores appeared on the nanorods. It was demonstrated that the porosity could be exploited to improve the visible light absorption of ZnO and reduce the bandgap from 3.11 eV to 2.99 eV. A combination of improved charge separation and transport of the heat-treated ZnO thus led to an increase in the photoelectrochemical properties. At an irradiation intensity of 100 mW/cm−2, the photocurrent density of the porous nanorod array was approximately 1.3 mA cm−2 at 1.2 V versus Ag/AgCl, which was five times higher than that of the ZnO nanorods. These results revealed the synthesis of promising porous ZnO nanorods for photoelectrochemical applications.


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