Nuclear magnetic resonance evidence for ion pairing in alkali-metal salts of 1,3-diphenylpropene

1970 ◽  
pp. 1256 ◽  
Author(s):  
J. W. Burley ◽  
R. Ife ◽  
R. N. Young
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Alkali Metal ◽  
Ion Pairing ◽  
Metal Salts ◽  
Alkali Metal Salts ◽  
Nuclear Magnetic

Nuclear magnetic resonance studies of alkali metal anions

1975 ◽  
Vol 79 (26) ◽  
pp. 3076-3079 ◽  
Author(s):  
James L. Dye ◽  
Charles W. Andrews ◽  
Joseph M. Ceraso
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Alkali Metal ◽  
Magnetic Resonance Studies ◽  
Metal Anions ◽  
Nuclear Magnetic

A 19F magic angle spinning nuclear magnetic resonance and infrared analysis of the adsorption of alkali metal fluorides onto montmorillonite clay

1990 ◽  
Vol 68 (8) ◽  
pp. 1420-1424 ◽  
Author(s):  
Fathi M. Asseid ◽  
Catherine V. A. Duke ◽  
Jack M. Miller
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Alkali Metal ◽  
Magic Angle Spinning ◽  
Montmorillonite Clay ◽  
Infrared Analysis ◽  
Magic Angle ◽  
Metal Fluorides ◽  
Angle Spinning ◽  
Nuclear Magnetic

Alkali metal fluorides have been adsorbed onto montmorillonite clay K10, and the resulting reagents analysed by 19F magic angle spinning nuclear magnetic resonance and infrared spectroscopy. The complexes M3SiF6, MAlF4, and M3AlF6 are readily formed, the particular complex depending on M, the loading, and the drying temperature employed. Chemisorption of fluoride to give surface -Si-F groups also occurs under certain conditions. Keywords: MAS NMR, alkali metal fluorides, adsorption, montmorillonite clay, infrared.

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