Activation energies for the elimination of hydrogen fluoride from alkyl fluorides obtained by the activated molecule and competitive shock-tube techniques

1970 ◽  
pp. 203 ◽  
Author(s):  
P. Cadman ◽  
M. Day ◽  
A. W. Kirk ◽  
A. F. Trotman-Dickenson
Keyword(s):  
Shock Tube ◽  
Hydrogen Fluoride ◽  
Activation Energies ◽  
Alkyl Fluorides

ChemInform Abstract: Base-Promoted Elimination of Hydrogen Fluoride from Alkyl Fluorides: Reactivity and Stereochemistry.

ChemInform ◽  
1988 ◽  
Vol 19 (40) ◽  
Author(s):  
S. MATSUBARA ◽  
H. MATSUDA ◽  
T. HAMATANI ◽  
M. SCHLOSSER
Keyword(s):  
Hydrogen Fluoride ◽  
Alkyl Fluorides

The Gas-Phase Pyrolysis of Nitrocyclobutanes: a Shock-Tube Investigation Supplemented with DFT Calculations of their Thermochemical and Structural Parameters

2001 ◽  
Vol 215 (9) ◽  
Author(s):  
Y.-X. Zhang ◽  
C.F. Wilcox ◽  
S.H. Bauer
Keyword(s):  
Dft Calculations ◽  
Shock Tube ◽  
Gas Phase ◽  
Structural Parameters ◽  
Activation Energies ◽  
Species Loss

Mono- and 1,1-dinitrocyclobutanes (highly diluted in Ar) were pyrolyzed at temperatures 860–1300 K in reflected shocks. Activation energies for their initial fragmentations were derived from measurements of relative rates of species loss, compared to cyclobutyl chloride and isopropyl bromide:

Base-promoted elimination of hydrogen fluoride from alkyl fluorides : Reactivity and stereochemistry

Tetrahedron ◽  
1988 ◽  
Vol 44 (10) ◽  
pp. 2855-2863 ◽  
Author(s):  
Seijiro Matsubara ◽  
Hiroyuki Matsuda ◽  
Takeshi Hamatani ◽  
Manfred Schlosser
Keyword(s):  
Hydrogen Fluoride ◽  
Alkyl Fluorides

Nucleophilic identity substitution reactions. The reaction between hydrogen fluoride and protonated alkyl fluorides

2006 ◽  
Vol 4 (1) ◽  
pp. 135-141 ◽  
Author(s):  
Jon K. Laerdahl ◽  
Pervin U. Civcir ◽  
Lihn Bache-Andreassen ◽  
Einar Uggerud
Keyword(s):  
Hydrogen Fluoride ◽  
Substitution Reactions ◽  
Alkyl Fluorides
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