Bichromophoric fluorescent photolabile protecting group for alcohols and carboxylic acids

2012 ◽  
Vol 11 (3) ◽  
pp. 518-521 ◽  
Author(s):  
Selvanathan Arumugam ◽  
Vladimir V. Popik
Keyword(s):  
Carboxylic Acids ◽  
Protecting Group ◽  
Photolabile Protecting Group

2-Hydroxy-1,2,2-triphenylethanone as an efficient photolabile protecting group for carboxylic acids

Tetrahedron ◽  
2007 ◽  
Vol 63 (3) ◽  
pp. 586-593 ◽  
Author(s):  
M. Arfan Ashraf ◽  
Alexander G. Russell ◽  
Christopher W. Wharton ◽  
John S. Snaith
Keyword(s):  
Carboxylic Acids ◽  
Protecting Group ◽  
Photolabile Protecting Group

2-Hydroxy-1,2,2-triphenylethanone as an Efficient Photolabile Protecting Group for Carboxylic Acids.

ChemInform ◽  
2007 ◽  
Vol 38 (21) ◽  
Author(s):  
M. Arfan Ashraf ◽  
Alexander G. Russell ◽  
Christopher W. Wharton ◽  
John S. Snaith
Keyword(s):  
Carboxylic Acids ◽  
Protecting Group ◽  
Photolabile Protecting Group

α-Carboxy-6-nitroveratryl: A Photolabile Protecting Group for Carboxylic Acids

2010 ◽  
Vol 75 (13) ◽  
pp. 4648-4651 ◽  
Author(s):  
Alexander G. Russell ◽  
Maria-Eleni Ragoussi ◽  
Rui Ramalho ◽  
Christopher W. Wharton ◽  
David Carteau ◽  
...  
Keyword(s):  
Carboxylic Acids ◽  
Protecting Group ◽  
Photolabile Protecting Group

Photolabile Protecting Group‐Mediated Synthesis of 2‐Deoxy‐Glycosides

2021 ◽  
Author(s):  
Xiaoqian Li ◽  
Zhi Ma ◽  
Rongkun Liu ◽  
Mattan Hurevich ◽  
You Yang
Keyword(s):  
Protecting Group ◽  
Photolabile Protecting Group

Novel Photolabile Protecting Group for Carbonyl Compounds

2007 ◽  
Vol 9 (8) ◽  
pp. 1533-1535 ◽  
Author(s):  
Pengfei Wang ◽  
Huayou Hu ◽  
Yun Wang
Keyword(s):  
Carbonyl Compounds ◽  
Protecting Group ◽  
Photolabile Protecting Group

scholarly journals Sunscreen-Assisted Selective Photochemical Transformations

Molecules ◽  
2020 ◽  
Vol 25 (9) ◽  
pp. 2125
Author(s):  
Or Eivgi ◽  
N. Gabriel Lemcoff
Keyword(s):  
Photochemical Reaction ◽  
Reaction Pathway ◽  
General Procedure ◽  
Molar Absorptivity ◽  
Photochemical Reactions ◽  
The Other ◽  
Protecting Group ◽  
Selective Reaction ◽  
Photochemical Transformations ◽  
Photolabile Protecting Group

In this review, we describe a simple and general procedure to accomplish selective photochemical reaction sequences for two chromophores that are responsive to similar light frequencies. The essence of the method is based on the exploitation of differences in the molar absorptivity at certain wavelengths of the photosensitive groups, which is enhanced by utilizing light-absorbing auxiliary filter molecules, or “sunscreens”. Thus, the filter molecule hinders the reaction pathway of the least absorbing molecule or group, allowing for the selective reaction of the other. The method was applied to various photochemical reactions, from photolabile protecting group removal to catalytic photoinduced olefin metathesis in different wavelengths and using different sunscreen molecules. Additionally, the sunscreens were shown to be effective also when applied externally to the reaction mixture, avoiding any potential chemical interactions between sunscreen and substrates and circumventing the need to remove the light-filtering molecules from the reaction mixture, adding to the simplicity and generality of the method.

A chemoselective photolabile protecting group for aldehydes

2020 ◽  
Vol 61 (14) ◽  
pp. 151709
Author(s):  
Jing Xu ◽  
Shouguo Zhang ◽  
Hongpeng Yang ◽  
Xiaoxue Wen ◽  
Tao Peng ◽  
...  
Keyword(s):  
Protecting Group ◽  
Photolabile Protecting Group
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