ZnO@ZIF-8: stabilization of quantum confined ZnO nanoparticles by a zinc methylimidazolate framework and their surface structural characterization probed by CO2 adsorption

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2018 ◽  
Vol 42 (23) ◽  
pp. 18526-18532 ◽  
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Si-Yuan Wang ◽  
Xin Dong ◽  
Jun-Fei Chen ◽  
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The tetranuclear iron molybdate Na6[(MoO2)2O2Fe2(nta)4]·16H2O (1) and its isomorphous complexes form 2D water layer structures in a modular manner, and a decanuclear heterometallic polymer, [(MoO4)2FeII4FeIII4(ida)8]n (2), contains an interesting cubic 3D microporous structure with a 3.3 Å diameter hole and can adsorb a small amount of CO2.


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